396102-32-2

Basic information

• Product Name: Benzene, 1,2-dimethoxy-5-methyl-3-(1,2,2-trimethylcyclopentyl)-
• CAS NO: 396102-32-2
• Molecular Formula: C17H26O2
• Molecular Weight: 262.392
• Mol File: 396102-32-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,2-dimethoxy-5-methyl-3-(1,2,2-trimethylcyclopentyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2-dimethoxy-5-methyl-3-(1,2,2-trimethylcyclopentyl)-(396102-32-2)
• EPA Substance Registry System: Benzene, 1,2-dimethoxy-5-methyl-3-(1,2,2-trimethylcyclopentyl)-(396102-32-2)

Safety Data

• Hazardous Substances Data: 396102-32-2(Hazardous Substances Data)

Upstream product

• 882512-75-6 2-[1-(2,3-dimethoxy-5-methylphenyl)-2,2-dimethylcyclopent-1-yl]acetaldehyde 
• 882512-66-5 1-(2,3-dimethoxy-5-methylphenyl)-2,2-dimethylpent-4-en-1-one 
• 882512-65-4 ethyl 2-[1-(2,3-dimethoxy-5-methylphenyl)-5,5-dimethylcyclopent-2-enyl]acetate 
• 882512-74-5 ethyl 2-[1-(2,3-dimethoxy-5-methylphenyl)-2,2-dimethylcyclopent-1-yl]acetate 
• 5497-67-6 2,2-dimethyl-4-pentenal 
• 93-51-6 2-Methoxy-4-methylphenol 
• 68278-85-3 3-bromo-4,5-dimethoxy-toluene 
• 5701-86-0 2,3-dimethoxy-5-methylbenzaldehyde 
• 396102-26-4 [1-(2',3'-dimethoxy-5'-methylphenyl)-2-methylcyclopent-2-enyl]methanol 
• 309751-04-0 3-(2,3-dimethoxy-5-methyl-phenyl)-2,2,3-trimethyl-hexanedioic acid dimethyl ester 
• 201359-55-9 1-(allyloxy)-2-methoxy-4-methylbenzene 
• 6948-30-7 5-bromoveratralaldehyde 
• 882512-64-3 ethyl 3-vinyl-3-(2,3-dimethoxy-5-methylphenyl)-4,4-dimethylhept-6-enoate 
• 882512-76-7 2-[1-(2,3-dimethoxy-5-methylphenyl)-2,2-dimethylcyclopent-1-yl]ethanol 

Downstream Products

• 86996-95-4 1,2-dihydroxy-5-methyl-3-(1',2',2'-trimethylcyclopentyl)benzene 

Relevant articles and documents

Total synthesis of (±)-herbertenediol

A formal total synthesis of the sesquiterpene (±)-herbertenediol and its dimers mastigophorenes A-D has been accomplished, starting from vanillin via 2,3-dimethoxy-5-methylbenzaldehyde. A combination of Claisen rearrangement and ring-closing metathesis reactions were employed for the generation of the two vicinal quaternary carbons on a cyclopentane ring.

New total synthesis of (±)-herbertene, (±)-β-herbertenol and (±)-herbertenediol

The total syntheses of the herbertane sesquiterpenes (±)-herbertene (1), (±)-β-herbertenol (2) and (±)-herbertenediol (5) have been successfully accomplished involving copper-catalysed conjugate addition of Grignard reagents to unsaturated compounds and α