39825-84-8

Basic information

• Product Name: 1-thiocyanatoadamantane
• Synonyms: 1-thiocyanatoadamantane
• CAS NO: 39825-84-8
• Molecular Weight: 193.313
• Mol File: 39825-84-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-thiocyanatoadamantane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-thiocyanatoadamantane(39825-84-8)
• EPA Substance Registry System: 1-thiocyanatoadamantane(39825-84-8)

Safety Data

• Hazardous Substances Data: 39825-84-8(Hazardous Substances Data)

Upstream product

• 2290-65-5 trimethylsilyl isothiocyanate 
• 935-56-8 1-chloroadamantane 
• 91233-19-1 1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione 
• 1424-52-8 p-tolylsulfonyl isothiocyanate 
• 768-95-6 1-adamanthanol 
• 1147550-11-5 ammonium thiocyanate 

Relevant articles and documents

Synthesis of Adamantane Derivatives. 56. Reaction of 1-Adamantyl Chloride with Trimethylsilyl Pseudohalide

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The invention of radical reactions. Part XXIII new reactions: Nitrile and thiocyanate transfer to carbon radicals from sulfonyl cyanides and sulfonyl isothiocyanates

Reaction of p-toluenesulphonyl cyanide or methanesulfonyl cyanide with carbon radicals, generated from the corresponding O-acyl-N-hydroxy-2-thiopyridone derivatives by visible light photolysis gives nitriles in good yield. The homolysis products of these sulfonyl nitriles can also be trapped by electron rich olefins. We have also found that carbon radicals react easily with mesyl or tosyl isothiocyanate producing thiocyanates.