39834-48-5Relevant articles and documents
Fe(III)-catalyzed trityl benzyl ether formation and disproportionation cascade reactions to yield benzaldehydes
Wang, Xiaoyu,Du, Chuan,Shi, Hui,Pang, Yadong,Jin, Shengfei,Hou, Yuqian,Wang, Yanshi,Peng, Xiaoshi,Xiao, Jianyong,Liu, Yang,Liu, Yongxiang,Cheng, Maosheng
, p. 6744 - 6748 (2015/08/24)
During investigating water-compatible Lewis acids catalyzed etherifications using alcohols as alkylating reagents directly, we developed Fe(III)-catalyzed trityl benzyl ether formations irradiated by microwave. Then an in situ trityl benzyl ether formation and disproportionation cascade reaction was achieved to yield the benzaldehyde products with good functional group tolerances under neat conditions at relative higher temperatures. The substituent effects of the substrates on the etherification and disproportionation were explored by changing the substitutions on benzyl alcohols and triarylmethanols using chemical kinetic plots methods and the mechanism of the transformation was studied by crossover experiments. The etherification and disproportionation cascade process could be conveniently scaled up in laboratory without losing much efficiency.
FeCl3-catalyzed tritylation of alcohols in ionic liquids
Sreedhar,Radhika,Neelima,Chowdary,Rao, M. V. Basaveswara
experimental part, p. 3785 - 3795 (2009/12/08)
A simple and efficient protection of alcohols as trityl ethers is described using trityl chloride in the presence of 5mol% FeCl3 as catalyst in ionic liquids at room temperature in shorter reaction times. This mild and efficient method gives access to the
