39924-30-6

Basic information

• Product Name: (Z)-4-Heptenoic acid methyl ester
• Synonyms: (Z)-4-Heptenoic acid methyl ester
• CAS NO: 39924-30-6
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 142.2
• Mol File: 39924-30-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 150.7±9.0 °C(Predicted)
• Appearance: /
• Density: 0.901±0.06 g/cm3(Predicted)
• CAS DataBase Reference: (Z)-4-Heptenoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-4-Heptenoic acid methyl ester(39924-30-6)
• EPA Substance Registry System: (Z)-4-Heptenoic acid methyl ester(39924-30-6)

Safety Data

• Hazardous Substances Data: 39924-30-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 21676-03-9 (Z)-3-hexenyl iodide 
• 201230-82-2 carbon monoxide 
• 13395-34-1 (3-(methoxycarbonyl)propyl)triphenylphosphonium bromide 
• 123-38-6 propionaldehyde 
• 82302-70-3 8-oxo-4Z-octenoic acid methyl ester 

Downstream Products

• 41653-95-6 (Z)-4-heptenoic acid 
• 20711-10-8 (Z)-11-tetradecenyl acetate 
• 6191-71-5 (Z)-4-hepten-1-ol 

Relevant articles and documents

Bidentate auxiliary-directed alkenyl C-H allylation: Via exo-palladacycles: Synthesis of branched 1,4-dienes

An alkenyl C-H allylation by an exo-palladacycle intermediate is demonstrated, employing unactivated (Z)-Alkenes and allyl carbonates. With the use of an 8-Aminoquinoline (AQ) derived amide as the directing group, the N,N-bidentate-chelation-Assisted C-H activation protocol proceeded under mild and oxidant-free conditions with excellent selectivity. The utility of this approach is demonstrated by the preparative scale, selective conversion of inseparable Z/E alkenes and ready removal of the amide auxiliary to provide the corresponding ester.

OZONOLYSIS OF ALKENES AND REACTIONS OF POLYFUNCTIONAL COMPOUNDS. XXXV. SYNTHESIS OF 8Z-DODECENYL- AND 11Z-TETRADECENYL ACETATES FROM THE CYCLIC DIMER OF BUTADIENE

The stereoselective synthesis of 8Z-dodecenyl- and 11Z-tetradecenyl acetates which are components of the sex pheromones of many species of insect of the order Lepidoptera, was realized on the basis of the partial ozonolysis of (Z,Z)-1,5-cyclooctadiene and its isomerization product (Z,Z)-1,3-cyclooctadiene.