40030-85-1

Basic information

• Product Name: bis-(4,4'-dimethyl-α'-oxo-bibenzyl-α-ylidene)-hydrazine
• Synonyms: bis-(4,4'-dimethyl-α'-oxo-bibenzyl-α-ylidene)-hydrazine
• CAS NO: 40030-85-1
• Molecular Weight: 472.587
• Mol File: 40030-85-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis-(4,4'-dimethyl-α'-oxo-bibenzyl-α-ylidene)-hydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: bis-(4,4'-dimethyl-α'-oxo-bibenzyl-α-ylidene)-hydrazine(40030-85-1)
• EPA Substance Registry System: bis-(4,4'-dimethyl-α'-oxo-bibenzyl-α-ylidene)-hydrazine(40030-85-1)

Safety Data

• Hazardous Substances Data: 40030-85-1(Hazardous Substances Data)

Upstream product

• 40030-78-2 4,4'-dimethylbenzil monohydrazone 
• 3457-48-5 1,2-di(4-methylphenyl)-1,2-ethanedione 
• 64-17-5 ethanol 
• 1218-89-9 4,4'-dimethylbenzoin 
• 139972-11-5 4,4'-dimethyl-benzoin-hydrazone 

Downstream Products

• 3457-48-5 1,2-di(4-methylphenyl)-1,2-ethanedione 
• 302-01-2 hydrazine 
• 4702-76-5 4,4'-dimethylbenzaldazine 
• 56186-26-6 4-Methyl-N-(2-oxo-1,2-di-p-tolyl-ethyl)-benzamide 

Relevant articles and documents

Formation of diazoketones and azines by improved oxidation of ketohydrazones using Cu(acac)2 as a catalyst

An efficient Cu(acac)2-catalyzed oxidation of ketohydrazones afforded the corresponding α-diazeketones or ketazines in high yields depending on the reaction conditions. However, the reaction of benzophenone hydrazone gave benzophenone azine without affording diphenyldiazomethane. The formation of azines is explained by intermediacy of carbenoid generated by the Cu(acac)2-catalyzed decomposition of diazo compounds.