40236-19-9Relevant articles and documents
Microwave-accelerated synthesis of benzyl 3,5-dimethyl-pyrrole-2- carboxylate
Regourd, Jasmine,Comeau, Ian M.,Beshara, Cory S.,Thompson, Alison
, p. 1709 - 1714 (2006)
Benzyl 3,5-dimethyl-pyrrole-2-carboxylate, a very useful pyrrole in porphyrin and dipyrromethene synthesis, can be synthesized via the Knorr-type reaction, but in low yield. Alternative routes to benzyl 3,5-dimethyl-pyrrole-2- carboxylate have been develo
Oxygen- and Carbon Monoxide-binding to a Lipophilic Diporphyrinatocopperiron Complex Solubilized in an Aqueous Medium with a Micelle
Nishide, Hiroyuki,Hashimoto, Yukio,Maeda, Hiromi,Tsuchida, Eishun
, p. 2963 - 2968 (2007/10/02)
A tetradecyl-substituted diporphyrinatocopperiron complex was synthesized and solubilized in an aqueous medium with a surfactant.Both the oxygen- and carbon monoxide-binding rate constants decreased due to the steric hindrance of the porphyrinatocopper cap, which brought about a reduced gas-binding affinity in comparison with other synthetic porphyrinatoiron complexes.
Novel Porphyrins from Copper(II)-Mediated Cyclizations of 1',8'-Dimethyl-a,c-biladiene Salts: Mechanism of the Cyclization Reaction
Smith, Kevin M.,Minnetian, Ohannes M.
, p. 2073 - 2080 (2007/10/02)
Copper(II)-mediated cyclizations of the 1',8'-dimethyl-a,c-biladiene 8 under various conditions afford the expected porphyrin 7, along with γ-methyl- (9), γ-(dialkylamino)- (10 and 11), 6-formyl- (12), and γ-formylporphyrins (13).Carbon-13-enriched a,c-bi