40296-93-3Relevant articles and documents
Preparation of alcohols from sulfones and trialkylboranes
Billaud, Célia,Goddard, Jean-Philippe,Le Gall, Thierry,Mioskowski, Charles
, p. 4451 - 4454 (2007/10/03)
The reaction of sulfone anions with trialkylboranes followed by thermal isomerization of the obtained boron compounds in the presence of excess borane-methyl sulfide complex and by alkaline hydroperoxide oxidation yields primary alcohols.
DENITROHYDROGENATION OF ALIPHATIC NITRO COMPOUNDS AND A NEW USE OF ALIPHATIC NITRO COMPOUNDS AS RADICAL PRECURSORS
Ono, Noboru,Miyake, Hideyoshi,Kamimura, Akio,Hamamoto, Isami,Tamura, Rui,Kaji, Aritsune
, p. 4013 - 4024 (2007/10/02)
Aliphatic nitro groups are replaced by hydrogen on treatment with tributyltin hydride which proceeds via free radical chain processes.As the nitro group is selectively denitrated and other reducible groups are not affected with tributyltin hydride, this reaction can be used as a method for removing the nitro group from polyfunctional compounds.The radical intermediates generated via denitration can be also used for the carbon-carbon bond forming reactions.