61777-12-6

Basic information

• Product Name: Benzene, (2-ethyl-3-methyl-1-butenyl)-
• Synonyms: 3-methyl-2-ethyl-1-phenyl-1-butene;Benzene,(2-ethyl-3-methyl-1-butenyl)
• CAS NO: 61777-12-6
• Molecular Formula: C13H18
• Molecular Weight: 174.28200
• Mol File: 61777-12-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 243.0±7.0 °C(Predicted)
• Density: 0.886±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzene, (2-ethyl-3-methyl-1-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-ethyl-3-methyl-1-butenyl)-(61777-12-6)
• EPA Substance Registry System: Benzene, (2-ethyl-3-methyl-1-butenyl)-(61777-12-6)

Safety Data

• Hazardous Substances Data: 61777-12-6(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 119925-04-1 2-{1-[1-Phenyl-meth-(E)-ylidene]-propyl}-[1,3]dithiolane 
• 74-83-9 methyl bromide 
• 40296-93-3 (Z,E)-2-methyl-1-phenylbut-2-ene 

Relevant articles and documents

NiCl2(dppe)-Catalyzed Geminal Dialkylation of Dithioacetals and Trimethylation of Ortho Thioesters

NiCl2(dppe)-catalyzed cross-coupling of cinnamaldehyde dithioacetals gave the corresponding geminal dimethylation products in excellent yields.Allylic ortho thioesters afforded regioselectively the corresponding trimethylation products.The reaction may occur via an 18-electron ?-allyl intermediate, which undergoes facile reductive elimination to afford the geminal dimethylation product.Benzylic dithioacetals having an ortho amino group gave 2-isopropylanilines exclusively.The reaction of benzylic dithioacetals with EtMgBr under the same conditions yielded geminal diethylation products.