41284-88-2Relevant articles and documents
Visible-light-induced oxidation/[3 + 2] cycloaddition/oxidative aromatization to construct benzo[ a]carbazoles from 1,2,3,4-tetrahydronaphthalene and arylhydrazine hydrochlorides
Shen, Jiaxuan,Li, Nannan,Yu, Yanjiang,Ma, Chunhua
supporting information, p. 7179 - 7183 (2019/09/30)
An efficient synthesis of benzo[a]carbazoles via visible-light-induced tandem oxidation/[3 + 2] cycloaddition/oxidative aromatization reactions was reported. The benzylic C(sp3)-H of tetrahydronaphthalene was activated through visible-light photoredox catalyst with oxygen as the clean oxidant under mild reaction conditions. This protocol proceeds efficiently with broad substrate scope, and the mechanism study was performed.
Concerted Catalysis by Adjacent Palladium and Gold in Alloy Nanoparticles for the Versatile and Practical [2+2+2] Cycloaddition of Alkynes
Miura, Hiroki,Tanaka, Yumi,Nakahara, Karin,Hachiya, Yuka,Endo, Keisuke,Shishido, Tetsuya
supporting information, p. 6136 - 6140 (2018/05/03)
A Pd-Au alloy efficiently catalyzed the [2+2+2] cycloaddition of substituted alkynes. Whereas monometallic Pd and Au catalysts were totally ineffective, Pd-Au alloy nanoparticle catalysts with a low Pd/Au molar ratio showed high activity to give the corresponding polysubstituted arenes in high yields. A variety of substituted alkynes participated in various modes of cycloaddition under Pd-Au alloy catalysis. The Pd-Au alloy catalysts exhibited high air tolerance and reusability.
Direct C-H bond arylation of arenes with aryltin reagents catalysed by palladium complexes
Kawai, Hiroshi,Kobayashi, Yasuhiro,Oi, Shuichi,Inoue, Yoshio
, p. 1464 - 1466 (2008/12/21)
Direct C-H bond arylation of simple arenes with aryltin reagents has been successfully catalysed by PdCl2 in the presence of CuCl2. CuCl2 proved to be an activator for a palladium intermediate as well as an oxidant. The Royal Society of Chemistry.