41317-87-7

Basic information

• Product Name: Benzene, 1,1'-(1-cyclohexene-1,2-diyl)bis-
• CAS NO: 41317-87-7
• Molecular Formula: C18H18
• Molecular Weight: 234.341
• Mol File: 41317-87-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-cyclohexene-1,2-diyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-cyclohexene-1,2-diyl)bis-(41317-87-7)
• EPA Substance Registry System: Benzene, 1,1'-(1-cyclohexene-1,2-diyl)bis-(41317-87-7)

Safety Data

• Hazardous Substances Data: 41317-87-7(Hazardous Substances Data)

Upstream product

• 3375-38-0 1,4-dibenzoylbutane 
• 124-04-9 Adipic acid 
• 849943-95-9 3,4,5,6-tetrahydro-[1,1'-biphenyl]-2-yl 4-methylbenzenesulfonate 
• 98-80-6 phenylboronic acid 
• 83859-60-3 1,6-diphenylhexane-1,6-diol 
• 1072-21-5 hexanedial 
• 100-59-4 phenylmagnesium chloride 
• 591-50-4 iodobenzene 
• 110-83-8 cyclohexene 
• 140903-04-4 1,6-Diphenyl-1,6-hexanedione dihydrazone 
• 111-50-2 Adipic acid dichloride 
• 71-43-2 benzene 
• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 591-51-5 phenyllithium 

Downstream Products

• 72930-73-5 cis-1,2-Diphenylcyclohexane-1,2-diol 

Relevant articles and documents

Base-Promoted/Gold-Catalyzed Intramolecular Highly Selective and Controllable Detosylative Cyclization

A highly selective, controllable and synthetically useful base-promoted intramolecular detosylative cyclization of bis-N-tosylhydrazones has been achieved, affording N-containing heterocycles and cyclic olefins under transition-metal-free or gold-catalyzed procedures, respectively. Moreover, an effective and practical metal-free or gold-catalyzed approach to synthesize polycyclic aromatic compounds is also reported. Basic cyclizations: A highly selective, controllable, and synthetically useful base-promoted intramolecular detosylative cyclization of bis-N-tosylhydrazones affords N-containing heterocycles and cyclic olefins under transition-metal-free or gold-catalyzed procedures, respectively. Moreover, an effective and practical metal-free or gold-catalyzed approach to synthesize polycyclic aromatic compounds is also reported.

A versatile palladium catalyst system for Suzuki-Miyaura coupling of alkenyl tosylates and mesylates

A general and effective palladium system for Suzuki-Miyaura coupling of alkenyl electrophiles under mild reaction conditions is reported. With the Pd(OAc)2/CM-phos system, a variety of alkenyl tosylates are coupled well with ArB(OH)2. Moreover, the first successful examples of using alkenyl mesylates in alkenylation are also described.

Well-defined air-stable palladium HASPO complexes for efficient Kumada-Corriu cross-couplings of (Hetero)aryl or alkenyl tosylates

Palladium complexes of representative heteroatom-substituted secondary phosphine oxide (HASPO) preligands were synthesized and fully characterized, including X-ray crystal structure analysis. Importantly, these well-defined complexes served as highly efficient catalysts for Kumada-Corriu cross-coupling reactions of aryl, alkenyl, and even heteroaryl tosylates. Particularly, an air-stable catalyst derived from inexpensive PinP(O)H displayed a remarkably high catalytic efficacy, which resulted in cross-couplings at low catalyst loadings under exceedingly mild reaction conditions with ample scope.