72930-73-5

Basic information

• Product Name: cis-1,2-Diphenylcyclohexane-1,2-diol
• Synonyms: cis-1,2-Diphenylcyclohexane-1,2-diol
• CAS NO: 72930-73-5
• Molecular Weight: 268.356
• Mol File: 72930-73-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: cis-1,2-Diphenylcyclohexane-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1,2-Diphenylcyclohexane-1,2-diol(72930-73-5)
• EPA Substance Registry System: cis-1,2-Diphenylcyclohexane-1,2-diol(72930-73-5)

Safety Data

• Hazardous Substances Data: 72930-73-5(Hazardous Substances Data)

Upstream product

• 4829-02-1 2-hydroxy-2-phenylcyclohexanone 
• 591-51-5 phenyllithium 
• 10316-66-2 2-hydroxy-2-cyclohexen-1-one 
• 23313-43-1 cis-acetic acid 2-hydroxy-2-phenyl-cyclohexyl ester 
• 4912-59-8 (1R,2R)-1-phenyl-1,2-cyclohexanediol 
• 765-87-7 cyclohexane-1,2-dione 
• 51128-50-8 2-[(trimethylsilyl)oxy]cyclohex-2-en-1-one 
• 100-58-3 phenylmagnesium bromide 
• 4829-02-1 (S)-(+)-2-hydroxy-2-phenylcyclohexanone 
• 83859-60-3 1,6-diphenylhexane-1,6-diol 
• 1072-21-5 hexanedial 
• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 65926-98-9 trans-1,2-Diphenylcyclohexane-1,2-diol 
• 3375-38-0 1,4-dibenzoylbutane 

Downstream Products

• 3375-38-0 1,4-dibenzoylbutane 

Relevant articles and documents

Reductive coupling of carbonyl compounds promoted by cobalt or titanium nanoparticles

The reaction of a series of aldehydes and ketones with readily prepared cobalt or titanium nanoparticles, under mild reaction conditions, led to the obtention of different reductive dimerization products depending on the nature of the transition metal used. Cobalt nanoparticles (CoNPs) allowed the selective transformation of the starting carbonyl compounds into vicinal diols, whereas the reaction promoted by titanium nanoparticles (TiNPs) led to the formation of the corresponding alkenes. In this last case, the use of trimethylsilyl chloride (TMSCl) as additive, at 0 °C, also allowed the obtention of vicinal diols after acidic aqueous work-up. ARKAT-USA, Inc.

Oxidative Cleavage of vic-Diols Using Copper(II) Bromide-Lithium t-Butoxide: A New Route to Unsymmetrical 1,5- and 1,6-Diketones

Unsymmetrical 1,6-diketones were obtained by the copper(II) bromide-lithium t-butoxide oxidation of 1,2-disubstituted 1,2-cyclohexanediols. The diols were easily prepared by the addition of Grignard reagents to 2-trimethylsiloxy-2-cyelohexenone followed by the hydrolysis and treatment of the resulting 2-hydroxycyclohexanones with the second Grignard reagents. Similarly, 1,5-Diketones were obtained using 2-trimethylsiloxy-2-cyclopentenone as a starting material.

Synthesis and Enantiomer Recognition of Crown Ethers containing Cyclohexane-1,2-diol Derivatives as the Chiral Centre and Enzymatic Resolution of the Chiral Subunits

The cyclohexane-1,2-diol derivatives 1 and 4 of high optical purity have been prepared by enantioselective hydrolysis of their acetates (+/-)-2 and (+/-)-5 using pig liver esterase.The enantiomer recognition behaviour of the chiral crown ethers 11, 14, 15