4912-59-8

Basic information

• Product Name: 1-phenylcyclohexane-1,2-diol
• Synonyms: 1-phenyl-1,2-cyclohexanediol; 1-Phenyl-trans-1,2-cyclohexanediol
• CAS NO: 4912-59-8
• Molecular Formula: C₁₂H₁₆O₂
• Molecular Weight: 192.2542
• Mol File: 4912-59-8.mol
• Article Data: 57

Chemical Properties

• Boiling Point: 322.7°C at 760 mmHg
• Flash Point: 153.7°C
• Density: 1.179g/cm³
• Vapor Pressure: 0.000113mmHg at 25°C
• Refractive Index: 1.592
• CAS DataBase Reference: 1-phenylcyclohexane-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylcyclohexane-1,2-diol(4912-59-8)
• EPA Substance Registry System: 1-phenylcyclohexane-1,2-diol(4912-59-8)

Safety Data

• Hazardous Substances Data: 4912-59-8(Hazardous Substances Data)

Upstream product

• 771-98-2 1-Phenylcyclohexene 
• 23313-43-1 cis-acetic acid 2-hydroxy-2-phenyl-cyclohexyl ester 
• 99942-90-2 2-Acetoxy-1-phenyl-cyclohexanol 
• 4829-01-0 (1R,2R)-1-phenyl-1-cyclohexene oxide 
• 4912-59-8 1-phenyl-1,2-cyclohexanediol 
• 1161819-40-4 (R)-2-(2-tolylaminooxy)cyclohexanone 
• 100-58-3 phenylmagnesium bromide 
• 4829-01-0 (-)-(1S,2S)-1-phenylcyclohex-1-ene oxide 
• 5775-23-5 1-phenylcyclohexene oxide 
• 1222099-34-4 (+/-)-2-(2-tolylaminooxy)cyclohexanone 
• 23313-45-3 acetic acid 2-acetoxy-2-phenylcyclohexyl ester 
• 4829-02-1 2-hydroxy-2-phenylcyclohexanone 

Downstream Products

• 134750-73-5 (-)-cis-2-(Methoxymethoxy)-1-phenylcyclohexanol 
• 134750-77-9 (-)-cis-4a-Phenyloctahydro-5,8,11,14,17,20-hexaoxabenzocyclooctadecane 
• 98919-68-7 (1R,2S)-trans-2-phenylcyclohexanol 
• 4829-02-1 (S)-(+)-2-hydroxy-2-phenylcyclohexanone 
• 134750-78-0 (-)-trans-4a,20a-Diphenyloctahydro-5,8,11,14,17,20-hexaoxabenzocyclooctadecane 
• 134875-74-4 (-)-trans-1,2-diphenylcyclohexane-1,2-diol 
• 134750-75-7 2,2'-Oxydiethylenedioxybis(2-phenylcyclohexanol) 
• 134750-74-6 (+)-2,2'-Oxydiethylenedioxybis(2-phenylcyclophenylethyl methyl ether) 
• 65926-98-9 trans-1,2-Diphenylcyclohexane-1,2-diol 
• 23313-43-1 cis-acetic acid 2-hydroxy-2-phenyl-cyclohexyl ester 
• 99344-07-7 cis-2-hydroxy-2-phenylcyclohexyl methanesulfonate 
• 134780-70-4 cis-1-Phenyl-2-acetoxylcyclohexanol 

Relevant articles and documents

Photo-Induced Dihydroxylation of Alkenes with Diacetyl, Oxygen, and Water

Herein reported is a photo-induced production of vicinal diols from alkenes under mild reaction conditions. The present dihydroxylation method using diacetyl (= butane-2,3-dione), oxygen, and water dispenses with toxic reagents and intractable waste generation.

Bronsted Acid Mediated Direct α-Hydroxylation of Cyclic α-Branched Ketones

We report a Bronsted acid mediated direct α-hydroxylation of cyclic α-branched ketones via a tandem aminoxylation/N-O bond-cleavage process. Nitrosobenzene is used as the oxidant and subsequently promotes the liberation of the free alcohol. The desired pr

Osmium on chelate resin: Nonvolatile catalyst for the synthesis of DIOLS from alkenes

Osmium tetraoxide (OsO4) was immobilized on a commercially available chelate resin DIAION CR11 (CR11) just by simply immersing it in a methanol solution of OsO4 at room temperature. The resulting purple solid, 5% Os/CR11, indicated no volatility, and effectively catalyzed the oxidation of various alkenes to the corresponding diols.