41841-01-4

Basic information

• Product Name: 2-Chloro-4''-methoxybenzil
• Synonyms: 2-Chloro-4''-methoxybenzil
• CAS NO: 41841-01-4
• Molecular Formula: C₁₅H₁₁ClO₃
• Molecular Weight: 274.69904
• Mol File: 41841-01-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 436.8°Cat760mmHg
• Flash Point: 180.6°C
• Appearance: /
• Density: 1.269g/cm³
• Vapor Pressure: 7.87E-08mmHg at 25°C
• Refractive Index: 1.588
• CAS DataBase Reference: 2-Chloro-4''-methoxybenzil(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Chloro-4''-methoxybenzil(41841-01-4)
• EPA Substance Registry System: 2-Chloro-4''-methoxybenzil(41841-01-4)

Safety Data

• Hazardous Substances Data: 41841-01-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H11ClO3/c1-19-11-8-6-10(7-9-11)14(17)15(18)12-4-2-3-5-13(12)16/h2-9H,1H3

Upstream product

• 5424-03-3 3-(2-chlorophenyl)-1-(4-methoxyphenyl)prop-2-en-1-one 
• 123-11-5 4-methoxy-benzaldehyde 
• 29568-74-9 2-chloro-N-hydroxybenzimidoyl chloride 
• 49660-38-0 2-chlorobenzonitrile oxide 
• 24588-72-5 2-(4-methoxyphenyl)-1,3-dithiane 
• 51512-09-5 2-(2-chlorophenyl)acetyl chloride 
• 2444-36-2 2'-chloro-benzeneacetic acid 
• 41840-95-3 2-(2-chlorophenyl)-1-(4-methoxyphenyl)ethanone 
• 41841-04-7 2-(2-chlorophenyl)-2-hydroxy-1-(4-methoxyphenyl)ethanone 
• 71-43-2 benzene 
• 74954-98-6 (2-Chloro-phenyl)-[2-(4-methoxy-phenyl)-[1,3]dithian-2-yl]-methanone oxime 

Downstream Products

• 41840-95-3 2-(2-chlorophenyl)-1-(4-methoxyphenyl)ethanone 
• 860572-35-6 α,α,2'-trichloro-4-methoxy-deoxybenzoin 

Relevant articles and documents

Copper-mediated aerobic oxidative cleavage of α,β-unsaturated ketones to 1,2-diketones

The copper-mediated aerobic oxidative cleavage of α,β- unsaturated ketones to synthesize 1,2-diketones by using potassium acetate as a catalyst and sodium iodide as a promoter in acetic acid is described. The protocol has the advantages of using inexpensive and non-toxic raw materials, high yield and simple work-up procedure. the Partner Organisations 2014.

Electrochemical oxidation of benzoins to benzils in the presence of a catalytic amount of KI in basic media

Various benzoins were transformed into the corresponding benzils via an electrochemical method. Although the strategy of oxidizing benzoins to the corresponding benzils is generally chosen depending on the nature of the aromatic moiety, the electrochemical technique reported herein allows oxidation that is widely applicable, and without the use of environmentally undesirable oxidants.

Silica supported manganese dioxide: An efficient reagent for oxidation of benzoins

A simple and practical method for the oxidative transformation of different benzoins to the corresponding benzils using silica supported manganese dioxide is described.