420089-28-7

Basic information

• Product Name: (2E,4E)-5-Phenyl-penta-2,4-dienoic acid methyl ester
• Synonyms: (2E,4E)-5-Phenyl-penta-2,4-dienoic acid methyl ester
• CAS NO: 420089-28-7
• Molecular Weight: 188.226
• Mol File: 420089-28-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (2E,4E)-5-Phenyl-penta-2,4-dienoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,4E)-5-Phenyl-penta-2,4-dienoic acid methyl ester(420089-28-7)
• EPA Substance Registry System: (2E,4E)-5-Phenyl-penta-2,4-dienoic acid methyl ester(420089-28-7)

Safety Data

• Hazardous Substances Data: 420089-28-7(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 273201-12-0 methyl bis(2,6-xylyl)phosphonoacetate 
• 4392-24-9 Cinnamyl bromide 
• 176437-60-8 (E)-methyl 2-diazo-5-phenylpent-4-enoate 
• 85217-77-2 2-acetyl-5-phenyl-pent-4-enoic acid methyl ester 
• 100-42-5 styrene 
• 123-73-9 trans-Crotonaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 5927-18-4 trimethyl phosphonoacetate 
• 88738-78-7 bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate 
• 96-32-2 bromoacetic acid methyl ester 

Downstream Products

• 70633-78-2 (3R,4E)-(-)-3-Hydroxy-5-phenyl-4-pentensaeure-methylester 
• 70633-77-1 (3S,4E)-(+)-3-Hydroxy-5-phenyl-4-pentensaeure-methylester 
• 185152-35-6 (4E)-5-phenylpenta-2,4-dienoic acid 

Relevant articles and documents

Enantioselective synthesis of 2-arylbicyclo[1.1.0]butane carboxylates

The rhodium-catalyzed reaction of 2-diazo-5-arylpent-4-enoates can be controlled by the appropriate choice of catalyst and catalyst loading to form either 2-arylbicyclo[1.1.0]butane carboxylates or cyclohexene derivatives. Both products are produced in a

Polymer-assisted solution-phase synthesis under combined ultrasound and microwave irradiation: Preparation of α,β-unsaturated esters and carboxylic acids, key intermediates of novel sigma ligands

The optimal conditions to prepare α,β-unsaturated methyl esters via Wittig reaction combining polymer-assisted solution-phase synthesis (PASPS) methodology and simultaneous ultrasound and microwave irradiation were established. The effects of temperature, solvent, and irradiation time were discussed. Results clearly indicated the superiority of combined ultrasound and microwave-assisted procedure over microwave-assisted methodology. Moreover, an efficient PASPS procedure to prepare α,β-unsaturated carboxylic acids via tandem Wittig olefination and hydrolysis reaction was developed under combined ultrasound and microwave irradiation. Generally, a good conversion of aldehydes to acids was observed. The optimized protocols allowed us to quickly prepare a small collection of either α,β-unsaturated esters or carboxylic acids, key intermediates for the drug-discovery process of new sigma ligands. Copyright Taylor & Francis Group, LLC.

Water is an efficient medium for Wittig reactions employing stabilized ylides and aldehydes

Water is demonstrated to be an excellent medium for the Wittig reaction employing stabilized ylides and aldehydes. Although the solubility in water appears to be an unimportant characteristic in achieving good chemical yields and E/Z-ratios, the rate of W