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4208-64-4

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4208-64-4 Usage

Description

1-(2-Furyl)ethanol, also known as (±)-2-Furyl methyl carbinol, is a furan derivative with a clear colorless to light yellow liquid appearance. It is an intermediate in the synthesis of various compounds and has been reported for its role in the creation of 4-hydroxy-2-methylcyclopent-2-en-1-one.

Uses

Used in Chemical Synthesis:
1-(2-Furyl)ethanol is used as an intermediate in the synthesis of 2H-Furo[2,3-c]pyran-2-one derivatives, which are known for their germination-promoting activity. This application is particularly relevant in the agricultural and pharmaceutical industries, where the promotion of plant growth and the development of new compounds with biological activity are of interest.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (±)-1-(2-Furyl)ethanol, or racemic 1-(2-furyl)ethanol, is used in the synthesis of 1-acetoxy-1-[2-furyl]ethan. 1-(2-FURYL)ETHAN-1-OL may have potential applications in the development of new drugs or pharmaceutical agents, contributing to the advancement of medical treatments and therapies.
Used in Research and Development:
Due to its role in the synthesis of various compounds, 1-(2-Furyl)ethanol is also utilized in research and development settings. Scientists and researchers may use this furan derivative to explore new chemical reactions, create novel molecules, and study their properties and potential applications in different fields, such as materials science, pharmaceuticals, and agriculture.

Check Digit Verification of cas no

The CAS Registry Mumber 4208-64-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,2,0 and 8 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 4208-64:
(6*4)+(5*2)+(4*0)+(3*8)+(2*6)+(1*4)=74
74 % 10 = 4
So 4208-64-4 is a valid CAS Registry Number.

4208-64-4 Well-known Company Product Price

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  • Aldrich

  • (48190)  (±)-1-(2-Furyl)ethanol  ≥99.0% (GC)

  • 4208-64-4

  • 48190-10ML-F

  • 1,656.72CNY

  • Detail

4208-64-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(2-FURYL)ETHAN-1-OL

1.2 Other means of identification

Product number -
Other names DL-1-(2-Furyl)ethanol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4208-64-4 SDS

4208-64-4Relevant articles and documents

A novel route to stereoselective synthesis of (4R,5S)-O- acetylosmundalactone and (4S,5R)-O-acetylosmundalactone

Yonghong, Gan,Fangning, Zhang,Xinfu, Pan

, p. 488 - 489 (1999)

A route has been developed for the enantioselective synthesis of (4R,5S)-O-acetylosmundalactone 1 and (4S,5R)-O-acetylosmundalactone 2 by using sharpless kinetic resolution of the racemic 1-(2-furyl)ethanol 6 as a key step.

Cationic Ru complexes anchored on POM via non-covalent interaction towards efficient transfer hydrogenation catalysis

Chen, Manyu,Cui, Kai,Hou, Zhenshan,Peng, Qingpo,Wang, Jiajia,Wei, Xinjia,Zhao, Xiuge

, (2021/12/22)

The ionic materials consisting of cationic Ru complexes and Wells-Dawson polyoxometalate anion (POM, K6P2W18O62) have been constructed via a non-covalent interaction. The as-synthesized catalysts have been characterized thoroughly by NMR, XRD, FESEM, and FT-IR, etc. The characterization suggested that a hydrogen bond interaction occurred between the proton of the amine ligand in the cationic Ru complexes and the oxygen atom of the POM anion. The hydrogen bond played an important role in enhancing catalytic activity for the transfer hydrogenation of methyl levulinate (ML) to γ-valerolactone (GVL) under very mild conditions. Especially, the transfer hydrogenation reaction proceeded via a heterogeneous catalysis approach and the heterogenized catalysts even afforded much better catalytic performance than homogeneous analogs. Notably, the catalysts can be recycled without an obvious loss of activity, and further extended to highly selective transfer hydrogenation of α,β-unsaturated ketones and aldehydes, etc. into the corresponding α,β-unsaturated alcohols without any base external additives. The high catalytic performance of these anchored catalysts was highly related to the hydrogen bond interaction and the basicity of the polyanion. The obtained knowledge from this work could lead us to a new catalysis concept of tethering active homogeneous complexes for constructing highly active anchored Ru complex catalysts for hydrogenation reaction.

2, 4, 5-Trideoxyhexopyranosides Derivatives of 4’-Demethylepipodophyllotoxin: De novo Synthesis and Anticancer Activity

Cai, Rui,Li, Yu,Lu, Yapeng,Zhao, Yu,Zhu, Li

, p. 130 - 139 (2022/03/09)

Background: Podophyllotoxin is a natural lignan which possesses anticancer and antiviral activities. Etoposide and teniposide are semisynthetic glycoside derivatives of podophyllotoxin and are increasingly used in cancer medicine. Objective: The present work aimed to design and synthesize a series of 2, 4, 5-trideoxyhexopyrano-sides derivatives of 4’-demethylepipodophyllotoxin as novel anticancer agents. Methods: A divergent de novo synthesis of 2, 4, 5-trideoxyhexopyranosides derivatives of 4’-demethylepipodophyllotoxin has been established via palladium-catalyzed glycosylation. The abili-ties of synthesized glycosides to inhibit the growth of A549, HepG2, SH-SY5Y, KB/VCR and HeLa cancer cells were investigated by MTT assay. Flow cytometric analysis of cell cycle with propidium iodide DNA staining was employed to observe the effect of compound 5b on cancer cell cycle. Results: Twelve D and L monosaccharide derivatives 5a-5l have been efficiently synthesized in three steps from various pyranone building blocks employing de novo glycosylation strategy. D-monosaccharide 5b showed the highest cytotoxicity on five cancer cell lines with the IC50 values ranging from 0.9 to 6.7 μM. It caused HepG2 cycle arrest at G2/M phase in a concentration-dependent manner. Conclusion: The present work leads to the development of novel 2, 4, 5-trideoxyhexopyranosides derivatives of 4’-demethylepipodophyllotoxin. The biological results suggest that the replacement of the glucosyl moiety of etoposide with 2, 4, 5-trideoxyhexopyranosyl is favorable to their cytotoxic-ity. D-monosaccharide 5b was observed to cause HepG2 cycle arrest at the G2/M phase in a concen-tration-dependent manner.

Reduction of carbonyl compounds via hydrosilylation catalyzed by well-defined PNP-Mn(I) hydride complexes

Weber, Stefan,Iebed, Dina,Glatz, Mathias,Kirchner, Karl

, p. 635 - 639 (2021/06/17)

Reduction reactions of unsaturated compounds are fundamental transformations in synthetic chemistry. In this context, the reduction of polarized double bonds such as carbonyl or C=C motifs can be achieved by hydrogenation reactions. We describe here a highly chemoselective Mn(I)-based PNP pincer catalyst for the hydrosilylation of aldehydes and ketones employing polymethylhydrosiloxane (PMHS) as inexpensive hydrogen donor. Graphic abstract: [Figure not available: see fulltext.]

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