42797-59-1

Basic information

• Product Name: Acetyl-(2,4,6-trimethylbenzoyl)-diazomethan
• Synonyms: Acetyl-(2,4,6-trimethylbenzoyl)-diazomethan
• CAS NO: 42797-59-1
• Molecular Weight: 230.266
• Mol File: 42797-59-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetyl-(2,4,6-trimethylbenzoyl)-diazomethan(CAS DataBase Reference)
• NIST Chemistry Reference: Acetyl-(2,4,6-trimethylbenzoyl)-diazomethan(42797-59-1)
• EPA Substance Registry System: Acetyl-(2,4,6-trimethylbenzoyl)-diazomethan(42797-59-1)

Safety Data

• Hazardous Substances Data: 42797-59-1(Hazardous Substances Data)

Upstream product

• 1667-01-2 2,4,6-Trimethylacetophenone 
• 6450-57-3 1-(2,4,6-trimethylphenyl)-1,3-butanedione 

Relevant articles and documents

An improved synthesis of 2-diazo-1,3-diketones

The sodium hydride/dibenzo-18-crown-6 ether system was found to be an effective base for the synthesis of 1,3-diketones by the Claisen condensation. The use of potassium fluoride (with or without crown ether) as the base in diazo-transfer reactions extends this reaction to the synthesis of hindered diazo diketones. In the case of isomeric 1,3-diketones, the stereoselectivity of the process considerably rises.