4537-11-5Relevant articles and documents
A novel catalyst for alkylation of benzene
Faghihian, Hossein,Mohammadi, Mohammad Hadi
, p. 962 - 968 (2012)
In this research, acid-activated and pillared montmorillonite were prepared as catalysts for alkylation of benzene with 1-decene for production of linear alkyl bebzene (LAB). The catalysts were characterized by X-ray diffraction (XRD), FT-IR spectroscopy,
Liquid phase alkylation of benzene with dec-1-ene catalyzed on supported 12-tungstophosphoric acid
Hernández-Cortez,Martinez,Soto,López,Navarrete,Manríquez,Lara,López-Salinas
scheme or table, p. 346 - 352 (2010/08/06)
The liquid phase alkylation of benzene with dec-1-ene was catalyzed by 12-tungstophosphoric acid (WP) supported on different solids (ZrO2, SiO2, activated carbon and boehmite-Al2O3). Catalysts prepared with 20 w
Catalytic Systems Based on Aluminum Chloride in Alkylation of Benzene with Olefins
Polubentseva,Duganova,Mikhailenko
, p. 614 - 618 (2007/10/03)
Two types of catalytic systems based on aluminum chloride and transition metal halides are prepared: mixed systems AlCl3-MeX (MeX is nickel, cobalt, copper, iron, tin, zinc, manganese, magnesium, potassium, or sodium chloride) and supported systems AlCl3/SiO2 and AlCl2·MeX/SiO2 (MeX is cobalt, nickel, or manganese chloride). Optimal conditions are found for preparation of catalytic systems based on aluminum chloride. These systems are studied in alkylation of benzene with olefins: ethene, propene, α-decene, and commercial C10-C14 fraction. Additives of nickel and cobalt chlorides increase the yield of ethyl- and propylbenzenes, simultaneously decreasing the yield of polyalkylbenzenes. Supported catalysts containing CoCl2, NiCl2, and FeCl3 additives increase the yield of monoalkylbenzenes in alkylation of benzene with higher olefins; additives of tin, zinc, and magnesium chlorides decrease the yield of monoalkylbenzenes; copper chloride is an inert additive. The yield of monoalkylbenzenes in alkylation of benzene with higher α-olefins in the presence of supported catalysts is 8-10% higher than in the presence of straight AlCl3. Preparation of supported catalytic systems requires 4-5 times smaller amount of aluminum chloride than preparation of binary systems.