459871-05-7

Basic information

• Product Name: methyl (S)-2-(((2S,4R)-4-((tert-butyldimethylsilyl)oxy)-6-oxotetrahydro-2H-pyran-2-yl)oxy)-2-phenylacetate
• Synonyms: methyl (S)-2-(((2S,4R)-4-((tert-butyldimethylsilyl)oxy)-6-oxotetrahydro-2H-pyran-2-yl)oxy)-2-phenylacetate
• CAS NO: 459871-05-7
• Molecular Weight: 394.54
• Mol File: 459871-05-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (S)-2-(((2S,4R)-4-((tert-butyldimethylsilyl)oxy)-6-oxotetrahydro-2H-pyran-2-yl)oxy)-2-phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (S)-2-(((2S,4R)-4-((tert-butyldimethylsilyl)oxy)-6-oxotetrahydro-2H-pyran-2-yl)oxy)-2-phenylacetate(459871-05-7)
• EPA Substance Registry System: methyl (S)-2-(((2S,4R)-4-((tert-butyldimethylsilyl)oxy)-6-oxotetrahydro-2H-pyran-2-yl)oxy)-2-phenylacetate(459871-05-7)

Safety Data

• Hazardous Substances Data: 459871-05-7(Hazardous Substances Data)

Upstream product

• 459870-97-4 4-(tert-butyl-dimethyl-silanyloxy)-tetrahydro-pyran-2,6-diol 
• 21210-43-5 (S)-Methyl mandelate 
• 459870-95-2 3-(tert-butyl-dimethyl-silanyloxy)-pentanedial 

Relevant articles and documents

Desymmetrisation of dialdehydes: (+)-(S) and (-)-(R) nor-methyl mevaldate as versatile synthetic intermediates

Desymmetrisation of 3-(t-butyldimethylsilyloxy)pentanedial 2 may be carried out by monoacetalisation with (R)- or (S)-2-phenylethanol. The products may be elaborated to nor-methyl mevaldate derivatives.