461051-85-4Relevant articles and documents
Tandem carbon-carbon bond constructions via catalyzed cyanation/Brook rearrangement/C-acylation reactions of acylsilanes
Linghu, Xin,Nicewicz, David A.,Johnson, Jeffrey S.
, p. 2957 - 2960 (2007/10/03)
(equation presented) A tandem nucleophile-catalyzed cyanation/Brook rearrangement/C-acylation has been developed. Phase transfer cocatalysts facilitate cyanide-catalyzed reactions between acylsilanes and cyanoformates to afford protected tertiary carbinol