462632-87-7

Basic information

• Product Name: 1-cyclohexyl-4-(tert-butyldimethylsilyloxy)-but-2-yne-1-ol
• Synonyms: 1-cyclohexyl-4-(tert-butyldimethylsilyloxy)-but-2-yne-1-ol
• CAS NO: 462632-87-7
• Molecular Weight: 282.498
• Mol File: 462632-87-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-cyclohexyl-4-(tert-butyldimethylsilyloxy)-but-2-yne-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-cyclohexyl-4-(tert-butyldimethylsilyloxy)-but-2-yne-1-ol(462632-87-7)
• EPA Substance Registry System: 1-cyclohexyl-4-(tert-butyldimethylsilyloxy)-but-2-yne-1-ol(462632-87-7)

Safety Data

• Hazardous Substances Data: 462632-87-7(Hazardous Substances Data)

Upstream product

• 76782-82-6 tert-Butyldimethyl(prop-2-ynyloxy)silane 
• 2043-61-0 cyclohexanecarbaldehyde 

Downstream Products

• 153489-62-4 4-cyclohexylbuta-2,3-dien-1-ol 
• 869810-43-5 4-cyclohexyl-4-(tetrahydro-2H-pyran-2-yloxy)-but-2-yn-1-ol 
• 869810-22-0 4-cyclohexylbuta-2,3-dien-1-yl acetate 
• 869810-42-4 1-(tert-butyldimethylsilyloxy)-4-cyclohexyl-4-(tetrahydro-2H-pyran-2-yloxy)-but-2-yne 

Relevant articles and documents

Stereoselective synthesis of (E)-β-tributylstannyl-α,β-unsaturated ketones: Construction of a key intermediate for the total synthesis of zoanthamine

(E)-β-Trialkylstannyl-α,β-unsaturated ketones are readily available from secondary propargylic alcohols via a two-step sequence involving highly regio- and stereoselective Pd(0)-catalyzed hydrostannation followed by mild oxidation (TPAP). The methodology

Dynamic kinetic asymmetric allylic alkylations of allenes

The dynamic kinetic asymmetric allylic alkylations of racemic allene acetates has been developed with the DACH-phenyl Trost ligand 2 to give general access to allenes with high enantiomeric excess (84-95%) for both malonate and amine nucleophiles. Further