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76782-82-6

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76782-82-6 Usage

Chemical Properties

Colorless Oil

Uses

Different sources of media describe the Uses of 76782-82-6 differently. You can refer to the following data:
1. tert-Butyldimethyl(2-propynyloxy)silane is an alkyne used in organinc synthesis.
2. tert-Butyldimethyl(2-propynyloxy)silane may be used in the synthesis of (R)-2,3-pentadecadien-1-ol and (S)-ethyl 5-(tert-butyldimethylsilyloxy)-2-hydroxy-2-phenylpent-3-ynoate.

General Description

tert-Butyldimethyl(2-propynyloxy)silane is an aliphatic terminal alkyne.

Check Digit Verification of cas no

The CAS Registry Mumber 76782-82-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,6,7,8 and 2 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 76782-82:
(7*7)+(6*6)+(5*7)+(4*8)+(3*2)+(2*8)+(1*2)=176
176 % 10 = 6
So 76782-82-6 is a valid CAS Registry Number.
InChI:InChI=1/C9H18OSi/c1-7-8-10-11(5,6)9(2,3)4/h1H,8H2,2-6H3

76782-82-6 Well-known Company Product Price

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  • (Code)Product description
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  • Packaging
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  • Detail
  • TCI America

  • (B5163)  tert-Butyldimethyl(2-propynyloxy)silane  >98.0%(GC)

  • 76782-82-6

  • 5mL

  • 490.00CNY

  • Detail
  • TCI America

  • (B5163)  tert-Butyldimethyl(2-propynyloxy)silane  >98.0%(GC)

  • 76782-82-6

  • 25mL

  • 1,490.00CNY

  • Detail
  • Aldrich

  • (495492)  tert-Butyldimethyl(2-propynyloxy)silane  97%

  • 76782-82-6

  • 495492-5ML

  • 616.59CNY

  • Detail
  • Aldrich

  • (495492)  tert-Butyldimethyl(2-propynyloxy)silane  97%

  • 76782-82-6

  • 495492-25ML

  • 2,122.38CNY

  • Detail

76782-82-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl-dimethyl-prop-2-ynoxysilane

1.2 Other means of identification

Product number -
Other names t-butyldimethylsilyl propargyl ether

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:76782-82-6 SDS

76782-82-6Relevant articles and documents

SuFEx on the Surface: A Flexible Platform for Postpolymerization Modification of Polymer Brushes

Yatvin, Jeremy,Brooks, Karson,Locklin, Jason

, p. 13370 - 13373 (2015)

Polymer brushes present a unique architecture for tailoring surface functionalities due to their distinctive physicochemical properties. However, the polymerization chemistries used to grow brushes place limitations on the monomers that can be grown direc

Synthesis and biological evaluation of novel non-racemic indole-containing allocolchicinoids

Shchegravina, Ekaterina S.,Maleev, Alexander A.,Ignatov, Stanislav K.,Gracheva, Iuliia A.,Stein, Andreas,Schmalz, Hans-Günther,Gavryushin, Andrey E.,Zubareva, Anastasiya A.,Svirshchevskaya, Elena V.,Fedorov, Alexey Yu.

, p. 51 - 60 (2017)

Two novel indole-containing allocolchicinoids were prepared from naturally occurring colchicine exploiting the Curtius rearrangement and tandem Sonogashira coupling/Pd-catalyzed cyclization as the key transformations. Their cytotoxic properties, apoptosis-inducing activity, tubulin assembly inhibition and short-time cytotoxic effects were investigated. Compound 7 demonstrated the most pronounced anti-cancer activity: IC50 1 nM, cell cycle arrest in the G2/M phase, 25% apoptosis induction, as well as lower destructive short-time effects on HT-29 cell line in comparison with colchicine. Docking studies for prepared indole-derived allocolchicine analogues were carried out.

Reverse Brook rearrangement of 2-alkynyl trialkylsilyl ether. Synthesis of optically active (1-hydroxy-2-alkynyl)trialkylsilane

Sakaguchi,Fujita,Suzuki,Higashino,Ohfune

, p. 6589 - 6592 (2000)

A new method for the synthesis of optically active α-hydroxyalkynylsilane 3 is described. The key step of the conversion to 3 was the use of the reverse Brook rearrangement of the 2-alkynyl silyl ether 2. (C) 2000 Elsevier Science Ltd.

Stereoselective formation of 1,4-dialkoxy-1,3-dienes from propargyl ethers and molybdenum carbene complexes

Harvey,Neil

, p. 2145 - 2150 (1993)

Under mild conditions 1,4-dialkoxy-1,3-butadienes can be smoothly prepared with a high level of stereoselectivity by thermolysis of molybdenum carbene complexes in the presence of propargyl ethers.

COMPOUNDS AND METHODS OF USE

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Page/Page column 220-221, (2022/03/09)

Disclosed are heterocyclic compounds or their pharmaceutically acceptable salts with ferroptosis-inducing activity, Those compounds or their pharmaceutically acceptable salts can be used to treat cancer.

PROBE FOR DETECTING CARBAPENEM-RESISTANT BACTERIA AND USE THEREOF

-

Paragraph 0085; 0096-0098, (2021/09/10)

The present disclosure relates to a compound represented by Chemical Formula 1, a probe for detecting antibiotic-resistant bacteria, which includes the compound, a composition containing the compound, a kit including the compound and a method for detectin

Regio-divergent nickel catalysis: intramolecular [4+2] and [2+2] cycloaddition reactions between vinylallenes and alkynes

Arai, Shigeru,Inagaki, Saki,Nakajima, Masaya,Nishida, Atsushi

supporting information, p. 11268 - 11271 (2021/11/03)

Vinylallenes have been recognized as versatile C2 and C4 components for nickel-catalyzed intramolecular [4+2] and [2+2] cycloadditions. The former reaction was promoted by a Ni(0) complex (up to quantitative yield), and a Ni(ii) salt was a key species for

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