536744-92-0

Basic information

• Product Name: 3-Pentyn-2-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-(phenylmethoxy)-
• CAS NO: 536744-92-0
• Molecular Formula: C18H28O3Si
• Molecular Weight: 320.504
• Mol File: 536744-92-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Pentyn-2-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentyn-2-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-(phenylmethoxy)-(536744-92-0)
• EPA Substance Registry System: 3-Pentyn-2-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-(phenylmethoxy)-(536744-92-0)

Safety Data

• Hazardous Substances Data: 536744-92-0(Hazardous Substances Data)

Upstream product

• 60656-87-3 benzyloxyacetoaldehyde 
• 76782-82-6 tert-Butyldimethyl(prop-2-ynyloxy)silane 

Downstream Products

• 536744-95-3 1-[5-benzyloxymethyl-1-(toluene-4-sulfonyl)-4-vinyl-2,5-dihydro-1H-pyrrol-3-yl]-ethanone 
• 536745-03-6 1-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-pent-3-yn-2-ol 
• 536745-00-3 2-[(3S,4R,5R)-4-[2-(Dimethyl-phenyl-silanyl)-ethyl]-5-hydroxymethyl-1-(toluene-4-sulfonyl)-pyrrolidin-3-yl]-1-trimethylsilanyl-propan-2-ol 
• 536744-97-5 1-[5-benzyloxymethyl-4-[2-(dimethylphenylsilanyl)ethyl]-1-(toluene-4-sulfonyl)-2,5-dihydro-1H-pyrrol-3-yl]ethanone 
• 536744-94-2 N-1-[benzyloxymethyl-4-(tertbutyldimethylsilanoxy)but-2-ynyl]-N-but-2-ynyl-4-methylbenzenesulfonamide 
• 536744-99-7 1-[4-[2-(dimethylphenylsilanyl)ethyl]-5-hydroxymethyl-1-(toluene-4-sulfonyl)pyrrolidin-3-yl]ethanone 
• 536744-98-6 1-[4-[2-(dimethylphenylsilanyl)ethyl]-5-hydroxymethyl-1-(toluene-4-sulfonyl)-2,5-dihydro-1H-pyrrol-3-yl]ethanone 
• 536745-04-7 3-carboxymethyl-4-isopropenyl-1-(toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid 
• 536745-01-4 2-[2-hydroxymethyl-4-isopropenyl-1-(toluene-4-sulfonyl)-pirrolidin-3-yl]-ethanol 
• 536744-93-1 1-benzyloxy-5-(tert-butyldimethylsilanoxy)pent-3-yn-2-one 

Relevant articles and documents

Ruthenium-catalyzed alkyne-propargyl alcohol addition. An asymmetric total synthesis of (+)-alpha-kainic acid.

A novel route to the neuroexcitatory amino acid, kainic acid, is developed. The key concept derives from a ruthenium-catalyzed cycloisomerization of a tethered alkyne-propargyl alcohol to form a cyclic 2-vinyl-1-acyl compound. A single stereocenter introd

Ruthenium-catalyzed cycloisomerizations of diynols

A wide variety of diynols containing tertiary, secondary, and primary propargylic alcohols undergo a cycloisomerization reaction to form dienones and dienals in the presence of a catalytic amount of [CpRu(CH3CN) 3]PF6. The