49593-34-2

Basic information

• Product Name: 1,2-diisopropoxy-1,2-diphenylethane
• Synonyms: 1,2-diisopropoxy-1,2-diphenylethane
• CAS NO: 49593-34-2
• Molecular Weight: 298.425
• Mol File: 49593-34-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,2-diisopropoxy-1,2-diphenylethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-diisopropoxy-1,2-diphenylethane(49593-34-2)
• EPA Substance Registry System: 1,2-diisopropoxy-1,2-diphenylethane(49593-34-2)

Safety Data

• Hazardous Substances Data: 49593-34-2(Hazardous Substances Data)

Upstream product

• 6652-28-4 benzoin isopropyl ether 
• 64713-81-1 O-isopropyl selenobenzoate 

Relevant articles and documents

Amphiphilic homopolymer as a reaction medium in water: Product selectivity within polymeric nanopockets

A styrene-based water-soluble polymer has been explored for its use as a host for lipophilic substrates in aqueous medium. Unimolecular reactions, namely, photo-Fries rearrangement of naphthyl esters, α-cleavage reaction of 1-phenyl-3-p-tolyl-propan-2-one, and Norrish type I and type II reactions of benzoin alkyl ethers were examined. We find that the hydrophobic domains generated by the polymer not only restrict the mobility of the radicals but also modestly incarcerate the substrate, intermediates, and products during the time scale of the reactions. Comparative studies of the same photoreactions in micelles formed from small molecule surfactants and an amphiphilic diblock copolymer demonstrate that the styrene-based water-soluble polymer aggregates in aqueous medium offer better selectivity.

Surface Photochemistry: Deviation of the Course of Reaction in Benzoin Ether Photolysis by Adsorption on Silica Gel

-