501093-00-1Relevant articles and documents
Serendipitous discovery of peptide dialkyl peroxides
Moretto, Alessandro,De Zotti, Marta,Scipionato, Laura,Formaggio, Fernando,Crisma, Marco,Toniolo, Claudio,Antonello, Sabrina,Maran, Flavio,Broxterman, Quirinus B.
, p. 3099 - 3112 (2002)
In an attempt to synthesize a homologous series of peptide peresters, we investigated the reaction of the oxazol-5(4H)-ones of Pht-(Aib)n-OH (n=2-8) and tert-butyl hydroperoxide in the presence of 4-(dimethylamino)pyridine. Unexpectedly, the ma