5106-98-9 Usage
Description
4-Chlorosalicylic acid is an organic compound that serves as a metabolite of the herbicide Benthiocarb and exhibits antifungal activity. It is characterized by the presence of a chlorine atom attached to the salicylic acid structure, which contributes to its unique properties and applications.
Uses
Used in Antifungal Applications:
4-Chlorosalicylic acid is used as an antifungal agent, effective against various fungal species. Its antifungal properties make it a potential candidate for use in agricultural and medical settings to control fungal infections and protect crops from fungal diseases.
Used in Chemical Analysis:
In the field of chemical analysis, 4-Chlorosalicylic acid is used for the sensitive spectrofluorometric determination of terbium in mixed rare earths. This application highlights its utility in analytical chemistry for the detection and quantification of specific elements.
Used in Polymer Synthesis:
4-Chlorosalicylic acid is also utilized in the preparation of poly(4-chlorosalicylic acid-formaldehyde) via condensation with formaldehyde. This polymer synthesis showcases its role in the creation of new materials with potential applications in various industries, such as plastics, coatings, and adhesives.
Biochem/physiol Actions
4-Chlorosalicylic acid shows potent antibacterial activity against Escherichia coli.
Check Digit Verification of cas no
The CAS Registry Mumber 5106-98-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,1,0 and 6 respectively; the second part has 2 digits, 9 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 5106-98:
(6*5)+(5*1)+(4*0)+(3*6)+(2*9)+(1*8)=79
79 % 10 = 9
So 5106-98-9 is a valid CAS Registry Number.
InChI:InChI=1/C7H5ClO3/c8-4-1-2-5(7(10)11)6(9)3-4/h1-3,9H,(H,10,11)/p-1
5106-98-9Relevant articles and documents
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Sheehan
, p. 1665 (1948)
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Carboxylation of o-, m-, and p-chlorophenols with sodium ethyl carbonate
Suerbaev, Kh. A.,Chepaikin,Kudaibergenov, N. Zh.
, p. 436 - 440 (2017/07/05)
The possibility for the synthesis of 5-chloro-2-hydroxybenzoic, 4-chloro-2-hydroxybenzoic, and 3-chloro-2-hydroxybenzoic acids via regioselective carboxylation of p-, m-, and o-chlorophenols, respectively, with sodium ethyl carbonate has been demonstrated
Regioselective ortho-carboxylation of phenols catalyzed by benzoic acid decarboxylases: A biocatalytic equivalent to the Kolbe-Schmitt reaction
Wuensch, Christiane,Gross, Johannes,Steinkellner, Georg,Lyskowski, Andrzej,Gruber, Karl,Glueck, Silvia M.,Faber, Kurt
, p. 9673 - 9679 (2014/03/21)
The enzyme catalyzed carboxylation of electron-rich phenol derivatives employing recombinant benzoic acid decarboxylases at the expense of bicarbonate as CO2 source is reported. In contrast to the classic Kolbe-Schmitt reaction, the biocatalytic equivalent proceeded in a highly regioselective fashion exclusively at the ortho-position of the phenolic directing group in up to 80% conversion. Several enzymes were identified, which displayed a remarkably broad substrate scope encompassing alkyl, alkoxy, halo and amino- functionalities. Based on the crystal structure and molecular docking simulations, a mechanistic proposal for 2,6-dihydroxybenzoic acid decarboxylase is presented.