51649-11-7

Basic information

• Product Name: Me₃SiNPPh₂CH₃
• Synonyms: Me₃SiNPPh₂CH₃
• CAS NO: 51649-11-7
• Molecular Weight: 287.417
• Mol File: 51649-11-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Me₃SiNPPh₂CH₃(CAS DataBase Reference)
• NIST Chemistry Reference: Me₃SiNPPh₂CH₃(51649-11-7)
• EPA Substance Registry System: Me₃SiNPPh₂CH₃(51649-11-7)

Safety Data

• Hazardous Substances Data: 51649-11-7(Hazardous Substances Data)

Upstream product

• 4648-54-8 trimethylsilylazide 
• 1486-28-8 diphenyl(methyl)phosphine 

Downstream Products

• 51715-46-9 C₂₄H₂₆NO₃PSi 
• 2290-65-5 trimethylsilyl isothiocyanate 
• 1242136-90-8 [AlCl₃(Me₃SiNPPh₂CH₃)] 
• 1242136-86-2 [(ZnCl(μ-Cl)(Me3SiNPPh2CH3))2] 
• 51649-14-0 C₁₅H₁₇N₂OP 
• 2129-89-7 diphenyl(methyl)phosphine oxide 
• 127802-65-7 1-aza-4-phospha-1-ethoxycarbonyl-4,4-diphenyl-2,3-dimethoxycarbonyl-1-penta-1,3-diene 
• 127802-69-1 2-[(Z)-Methoxycarbonylimino]-3-(methyl-diphenyl-λ⁵-phosphanylidene)-succinic acid dimethyl ester 
• 127802-74-8 1-aza-4,4-diphenyl-5,6-dimethoxycarbonyl-2-oxo-4λ⁵-phosphinine 
• 127802-79-3 2-(Methyl-diphenyl-λ⁵-phosphanylidene)-3-[(Z)-trimethylsilanyl-imino]-succinic acid dimethyl ester 
• 54123-98-7 C₁₃H₁₃N₄PS₃ 
• 66055-12-7 (Cyanimino)methyldiphenylphosphoran 
• 51649-15-1 C₁₉H₂₇N₂OPSi 
• 30543-46-5 N-phenyl-N'-(trimethylsilyl)carbodiimide 

Relevant articles and documents

Reactions of α-lithiated phosphimines with PhCN; the crystal structure of (tmen)>2 (tmen = Me2NCH2CH2NMe2)

Treatment of the α-lithiated phosphinimine Li with benzonitrile yielded (via a trimethylsilyl or hydrogen 1,3 C -> N shift) the trimethylsilyliminophosphoranylenamidolithium complex Li (R = Me, R' = SiMe3 1; R = Ph, R' = SiMe3 2; or R = Ph, R' = H 3).Complex 2 was transformed into the corresponding potassium complex 4 by an exchange reaction with KOBut.Crystallisation of 4 from hexane in the presence of Me2NCH2CH2NMe2 (tmen) gave the tmen adduct 5 and a trace of the partially hydrolysed product (tmen)>2 6, which was characterised by a single crystal X-ray diffraction study as a dinuclear complex with each of the two potassium atoms in a different co-ordination environment.Complex 1 or 2 was hydrolysed to form the neutral iminophosphoranylenamine N(SiMe3)C(Ph)C(H)P(R)2N(SiMe3)H 7 or 8, which also showed (1H NMR spectroscopy) the presence of hydrogen bonds.