5209-18-7

Basic information

• Product Name: Propene, 1,3-diphenyl- (8CI)
• CAS NO: 5209-18-7
• Molecular Formula: C₁₅H₁₄
• Molecular Weight: 194.276
• Mol File: 5209-18-7.mol
• Article Data: 123

Chemical Properties

• CAS DataBase Reference: Propene, 1,3-diphenyl- (8CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Propene, 1,3-diphenyl- (8CI)(5209-18-7)
• EPA Substance Registry System: Propene, 1,3-diphenyl- (8CI)(5209-18-7)

Safety Data

• Hazardous Substances Data: 5209-18-7(Hazardous Substances Data)

Upstream product

• 329-98-6 phenylmethylsulphonyl fluoride 
• 122-78-1 phenylacetaldehyde 
• 33417-25-3 Benzylbenzylidendiphenylphosphoran 
• 54098-14-5 Tribenzylbenzylidenphosphoran 
• 75619-30-6 Benzylidene-tris-(4-methoxy-phenyl)-λ⁵-phosphane 
• 864078-99-9 C₃₁H₃₆N₃P 
• 16721-45-2 triphenyl(phenylmethylene)phosphorane 
• 105512-32-1 3-Methoxy-1-phenylthio-1-propene 
• 4392-24-9 Cinnamyl bromide 
• 95576-66-2 phenyltriethoxytitanium 
• 886-38-4 diphenylcyclopropenone 
• 105-58-8 Diethyl carbonate 
• 5381-92-0 1,3-diphenylpropan-2-ol 
• 591-50-4 iodobenzene 

Downstream Products

• 170277-50-6 2-benzyl-3-phenyloxirane 
• 56363-42-9 1,2-dibromo-1,3-diphenyl-propane 
• 1081-75-0 1,3-diphenylpropane 
• 3178-24-3 1,1'-(1,3-propanediyl)biscyclohexane 
• 2294-90-8 1,3-diphenyl-2-propene-1-carboxylic acid 
• 14213-83-3 1-benzyl-trans-2-phenylcyclopropane 
• 62753-15-5 3-nitro-1,3-diphenyl-1-propene 
• 34862-96-9 3-bromro-1,3-diphenyl-1-propene 
• 24547-81-7 2-Deuterio-1,3-diphenylpropen 
• 147098-52-0 (Z,E)-1,3-Diphenylallyl-Anion 
• 103980-89-8 1,3-diphenyl-1-(trichlorosilyl)propane 
• 100-52-7 benzaldehyde 
• 1235117-78-8 ((1E,4E)-5-bromo-5-(4-chlorophenyl)penta-1,4-diene-1,3-diyl)dibenzene 
• 1235117-65-3 ((1E,4E)-5-chloro-5-(4-chlorophenyl)penta-1,4-diene-1,3-diyl)dibenzene 

Relevant articles and documents

Nickel-Catalyzed Electrochemical C(sp3)?C(sp2) Cross-Coupling Reactions of Benzyl Trifluoroborate and Organic Halides**

Reported here is the redox neutral electrochemical C(sp2)?C(sp3) cross-coupling reaction of bench-stable aryl halides or β-bromostyrene (electrophiles) and benzylic trifluoroborates (nucleophiles) using nonprecious, bench-stable NiCl2?glyme/polypyridine catalysts in an undivided cell configuration under ambient conditions. The broad reaction scope and good yields of the Ni-catalyzed electrochemical coupling reactions were confirmed by 50 examples of aryl/β-styrenyl chloride/bromide and benzylic trifluoroborates. Potential applications were demonstrated by electrosynthesis and late-stage functionalization of pharmaceuticals and natural amino acid modification, and three reactions were run on gram-scale in a flow-cell electrolyzer. The electrochemical C?C cross-coupling reactions proceed through an unconventional radical transmetalation mechanism. This method is highly productive and expected to find wide-spread applications in organic synthesis.

METHOD FOR PRODUCING ARENE COMPOUNDS AND ARENE COMPOUNDS PRODUCED BY THE SAME

Provided is a method for producing (alkyl)arene compounds represented by Formulae 3-1, 3-2, and 3-3 by the Friedel-Crafts alkylation reaction of alkyl halide compounds and arene compounds using organic phosphine compounds as a catalyst.

Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl Halides

As alcohols are ubiquitous throughout chemical science, this functional group represents a highly attractive starting material for forging new C-C bonds. Here, we demonstrate that the combination of anodic preparation of the alkoxy triphenylphosphonium ion and nickel-catalyzed cathodic reductive cross-coupling provides an efficient method to construct C(sp2)-C(sp3) bonds, in which free alcohols and aryl bromides - both readily available chemicals - can be directly used as coupling partners. This nickel-catalyzed paired electrolysis reaction features a broad substrate scope bearing a wide gamut of functionalities, which was illustrated by the late-stage arylation of several structurally complex natural products and pharmaceuticals.