52112-26-2Relevant articles and documents
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Swisher,J.V.,Chen,H.-H.
, p. 93 - 103 (1974)
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Synthesis of 2-methylidene-1-silacyclohexanes by intramolecular hydrosilylation
Díez-González, Silvia,Blanco, Luis
, p. 2033 - 2040 (2008/09/19)
The preparation of various (hex-5-ynyl)silanes was achieved following two different synthetic approaches from readily available materials such as 4-bromobutene, 6-iodohexyne and chlorosilanes. Different reaction conditions for intramolecular hydrosilylation were tested to prepare the corresponding 2-methylidene-1-silacyclohexanes. Notably, the use of Speier's catalyst allowed the regioselective formation of the desired products in moderate yields.
Greffage d'un modele du NADH sur silice : etude de la reactivite et utilisation en synthese asymetrique
Bourguignon, Jean,Tintillier, Patrick,Trefouel, Thierry,Losset, Denis,Dupas, Georges,Queguiner, Guy
, p. 264 - 266 (2007/10/02)
A NADH model was grafted on a silica matrix.The obtained reagent is efficient in synthesis.The reactivity of the reagent was studied as a function of the length of the chain between the reagent and the surface of the support.A chiral reagent was synthesized and used in asymmetric reactions.Good enantiomeric excesses were obtained.