52271-41-7Relevant articles and documents
Electrooxidative Dearomatization to Spiroisoxazolines: Application to Total Synthesis of Xanthoisoxazoline B
Chen, Dengfeng,He, Tianyu,Jin, Yongcan,Huang, Shenlin
supporting information, p. 286 - 290 (2021/11/13)
The synthesis of spiroisoxazoline molecules has been developed via anodic oxidative dearomatization of 4-methoxybenzyl oximes. The reaction is thought to proceed through 5-exo C?O bond-forming cyclization of oxime radicals with arenes on the basis of cycl
ASPARAGINE DERIVATIVES AND METHODS OF USE THEREOF
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Paragraph 00733-00734, (2021/12/31)
The present invention relates to compounds of formulas (A) and (I), pharmaceutically acceptable salts thereof, and solvates of any of them, pharmaceutical compositions comprising them, methods of preparation thereof, intermediate compounds useful for the preparation thereof, and methods of treatment or prophylaxis of diseases, in particular cancer, such as colorectal cancer, using these. (A) (I)
Solvents inducing oxidation of hydroxylamines
Horiyama, Shizuyo,Suwa, Kiyoko,Yamaki, Masae,Kataoka, Hiromi,Katagi, Toyoshi,Takayama, Mitsuo,Takeuchi, Takae
, p. 996 - 1000 (2007/10/03)
Hydroxylamines gradually undergo oxidation to their oximes on being dissolved in organic solvent (e.g. methanol). This phenomenon was followed by 1H-NMR and liquid chromatography-mass spectrometry (LC-MS). The oxidation rate was estimated from