52707-50-3

Basic information

• Product Name: Benzaldehyde, 3-methyl-, oxime, (E)- (9CI)
• Synonyms: Benzaldehyde, 3-methyl-, oxime, (E)- (9CI)
• CAS NO: 52707-50-3
• Molecular Formula: C₈H₉NO
• Molecular Weight: 135.16316
• Product Categories: OXIME
• Mol File: 52707-50-3.mol
• Article Data: 59

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzaldehyde, 3-methyl-, oxime, (E)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 3-methyl-, oxime, (E)- (9CI)(52707-50-3)
• EPA Substance Registry System: Benzaldehyde, 3-methyl-, oxime, (E)- (9CI)(52707-50-3)

Safety Data

• Hazardous Substances Data: 52707-50-3(Hazardous Substances Data)

Upstream product

• 620-23-5 m-tolyl aldehyde 
• 109423-08-7 1,3,5-tris(m-tolyl)perhydro-1,3,5-triazine 
• 108-44-1 1-amino-3-methylbenzene 
• 100-81-2 3-methyl-benzenemethanamine 
• 15728-26-4 2-(3-methylbenzylidene)malononitrile 
• 587-03-1 3-methylbenzyl alcohol 
• 591-17-3 meta-bromotoluene 
• 68-12-2 N,N-dimethyl-formamide 
• 104-87-0 4-methyl-benzaldehyde 

Downstream Products

• 1613642-64-0 C₂₆H₂₀N₂O₂ 
• 1613642-65-1 C₂₈H₁₈N₄O₂ 
• 1613643-09-6 C₂₈H₂₆N₄O₂ 
• 1613643-10-9 C₃₀H₃₀N₈O₂ 
• 3441-00-7 5-(3-methylphenyl)-1H-tetrazole 
• 26166-63-2 1-dinitromethyl-3-methyl-benzene 
• 620-23-5 m-tolyl aldehyde 
• 134589-64-3 Bis-[1-m-tolyl-meth-(Z)-ylidene]-diazene N,N'-dioxide 
• 90732-97-1 Phenyl-(5-m-tolyl-[1,2,4]oxadiazol-3-yl)-methanone 
• 26995-44-8 3-methyl-benzaldehyde (E)-O-(1,1-dioxo-1H-1λ⁶-benzo[d]isothiazol-3-yl)-oxime 
• 100-81-2 3-methyl-benzenemethanamine 
• 692771-01-0 5-(2-fluorophenyl)-3-(3-methylphenyl)-1,2,4-oxadiazole 
• 111249-50-4 3-(3-methylphenyl)-5-phenyl-1,2,4-oxadiazole 

Relevant articles and documents

On the mixed oxides-supported niobium catalyst towards benzylamine oxidation

A series of mixed oxides-supported niobium-based catalysts has been synthesized and applied towards oxidation reactions of benzylamine derivatives. Under the optimized reaction conditions, the selectivity to oxime enhanced, leading to the main product with up to 72 %. Moreover, even α-substituted benzylamines were well tolerated and led to oximes in good isolated yields. It is important to mention; four equivalents of the harmless and inexpensive hydrogen peroxide were employed as oxidizing agent. Mechanism hypothesis suggested that the reaction proceed to selective benzylamine oxidation into nitroso intermediate, following by formation of the corresponding oxime tautomer mediated by an unstable water produced by NbOx supported catalyst. This consists the first mixed oxides-supported niobium-based catalyst for selective oxidation of benzylamines to oximes.

Ru-Catalyzed [3 + 2] Cycloaddition of Nitrile Oxides and Electron-Rich Alkynes with Reversed Regioselectivity

Polarity reversal ("umpolung") of a functional group can override its inherent reactivity and lead to distinct bond-forming modes. Herein we describe a rarely studied cycloaddition between nitrile oxides and electron-rich alkynes with reversed regioselect

Electrochemical synthesis of 1,2,4-oxadiazoles from amidoximes through dehydrogenative cyclization

A convenient and efficient method for the generation of the iminoxy radical through anodic oxidation was developed for the synthesis of 3,5-disubstituted 1,2,4-oxadiazoles fromN-benzyl amidoximes. The transformation proceeds through 1.5-Hydrogen Atom Transfer (1,5-HAT) and intramolecular cyclization. The process features simple operation, mild conditions, broad substrate scope and high functional group compatibility, and provides a facile and practical way for the preparation of 1,2,4-oxadiazoles.