5284-13-9

Basic information

• Product Name: (3E)-2-hydroxy-1-phenylthio-3-pentene
• Synonyms: (3E)-2-hydroxy-1-phenylthio-3-pentene
• CAS NO: 5284-13-9
• Molecular Weight: 194.298
• Mol File: 5284-13-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3E)-2-hydroxy-1-phenylthio-3-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: (3E)-2-hydroxy-1-phenylthio-3-pentene(5284-13-9)
• EPA Substance Registry System: (3E)-2-hydroxy-1-phenylthio-3-pentene(5284-13-9)

Safety Data

• Hazardous Substances Data: 5284-13-9(Hazardous Substances Data)

Upstream product

• 123-73-9 trans-Crotonaldehyde 
• 13307-75-0 (phenylthio)methyllithium 
• 7205-91-6 phenylthiomethyl chloride 
• 79345-32-7 (E)-CH₃CH=CHCH₂ONa 
• 100-68-5 methyl-phenyl-thioether 
• 123-73-9 crotonaldehyde 

Downstream Products

• 137346-03-3 methyl (E)-2,2-dimethyl-3-phenylthiomethyl-4-hexenoate 
• 137346-11-3 methyl (E)-2,2,3-trimethyl-3-phenylthio-4-hexenoate 
• 137371-19-8 (E)-2,2-dimethyl-5-phenylthiomethyl-6-octen-3-one 
• 137346-04-4 (E)-4-phenylthiomethyl-1,5-heptadiene 
• 137346-18-0 (E)-2-Acetoxy-1-phenylthio-3-pentene 
• 83333-89-5 (E)-5-(phenylthio)-1,3-pentadiene 
• 83334-06-9 (Z)-5-(phenylthio)-1,3-pentadiene 

Relevant articles and documents

A Highly Regioselective Reaction of Allylic Acetates with Silylated Carbon Nucleophiles Directed by a Sulfenyl Group. Scope, Limitation, and Mechanistic Aspects

α-(Sulfenylmethyl)allyl acetates reacted with silylated carbon nucleophiles in the presence of a catalytic amount of TMSOTf to give products substituted at the α-position of the sulfenylmethyl group in moderate to good yields with high regioselectivity.The theoretical calculation on an intermediate cationic species indicated that an episulfonium ion was a stable form; the observed regioselectivity was rationalized qualitatively on the basis of the coefficients of LUMO of the cation.Some transformations of the products were also demonstrated.

Reaction of Alkoxides with (Phenylthio)carbene: A Novel Oxyanionic Substituent Effect on the C-H Insertion of Carbenes

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