53347-52-7Relevant articles and documents
Copper-Catalyzed Borylacylation of Activated Alkenes with Acid Chlorides
Huang, Yuan,Smith, Kevin B.,Brown, M. Kevin
, p. 13314 - 13318 (2017)
A method for the copper-catalyzed borylacylation of activated alkenes is presented. The reaction involves borylcupration of the alkene, followed by capture of the generated alkyl–copper intermediate with an acid chloride. The reactions operated with low catalyst loading and generally occurre within 15 min at room temperature for a range of activated alkenes. In the case of vinyl arenes, enantioselective borylacylation was possible.
2,3-Diarylindenes and 2,3-diarylindenones: Synthesis, molecular structure, photochemistry, estrogen receptor binding affinity, and comparisons with related triarylethylenes
Anstead,Altenbach,Wilson,Katzenellenbogen
, p. 1316 - 1326 (2007/10/02)
Two 2,3-diphenylindene and -indenone systems, with potential fluorescent and photofluorogenic properties, were prepared and studied as ligands for the estrogen receptor. The indene systems were prepared by Friedel-Crafts cyclization of appropriate α-benzy
