53722-39-7

Basic information

• Product Name: N,N'-di-isopropylbenzamidine
• Synonyms: N,N'-di-isopropylbenzamidine
• CAS NO: 53722-39-7
• Molecular Weight: 204.315
• Mol File: 53722-39-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N,N'-di-isopropylbenzamidine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-di-isopropylbenzamidine(53722-39-7)
• EPA Substance Registry System: N,N'-di-isopropylbenzamidine(53722-39-7)

Safety Data

• Hazardous Substances Data: 53722-39-7(Hazardous Substances Data)

Upstream product

• 807329-97-1 TurboGrignard 
• 4222-25-7 3-bromo-3-phenyl-3H-diazirine 
• 591-51-5 phenyllithium 
• 693-13-0 diisopropyl-carbodiimide 

Relevant articles and documents

Radical and Nitrenoid Reactivity of 3-Halo-3-phenyldiazirines

3-Halo-3-phenyl-3H-diazirines (halogen = Br or Cl) undergo a dissociative single-electron transfer from alkyllithiums (RLi) in THF-based solvent mixtures. The resulting 3-phenyldiazirinyl radical, observed by EPR spectroscopy, is eventually transformed to benzonitrile. In Et2O, 2 equiv of RLi add to both nitrogens of halodiazirine N=N bond, affording N,N′-dialkylbenzamidines. The nitrenoid reactivity of some N-alkyl-1H-diazirine intermediates is manifested by their insertion into the α-C-H bond of THF or Et2O.