807329-97-1 Usage
Description
ISOPROPYLMAGNESIUM CHLORIDE LITHIUM CHL& is a chemical compound that is commonly used in various organic synthesis processes. It is known for its ability to facilitate regioselective functionalization, electrophilic amination, and the preparation of various organic compounds.
Uses
Used in Organic Synthesis:
ISOPROPYLMAGNESIUM CHLORIDE LITHIUM CHL& is used as a reagent for the regioselective functionalization of trisubstituted pyridines, which is important for the synthesis of various pharmaceutical and agrochemical compounds.
Used in Amination Reactions:
It is used as an electrophilic aminating agent for the preparation of amines and functionalization of cyclopentene derivatives. This is crucial for the synthesis of various organic compounds, including pharmaceuticals and agrochemicals.
Used in Heterocyclic Compound Synthesis:
ISOPROPYLMAGNESIUM CHLORIDE LITHIUM CHL& is used in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. These heterocyclic compounds are important building blocks in the synthesis of various organic compounds, including pharmaceuticals and agrochemicals.
Used in Benzylic Grignard Synthesis:
It is used in the synthesis of benzylic Grignards via sulfur-magnesium exchange. This is an important method for the preparation of various organic compounds, including pharmaceuticals and agrochemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 807329-97-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,0,7,3,2 and 9 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 807329-97:
(8*8)+(7*0)+(6*7)+(5*3)+(4*2)+(3*9)+(2*9)+(1*7)=181
181 % 10 = 1
So 807329-97-1 is a valid CAS Registry Number.
807329-97-1Relevant articles and documents
Regioselective Bromine/Magnesium Exchange for the Selective Functionalization of Polyhalogenated Arenes and Heterocycles
Desaintjean, Alexandre,Haupt, Tobias,Bole, Leonie J.,Judge, Neil R.,Hevia, Eva,Knochel, Paul
supporting information, p. 1513 - 1518 (2020/11/30)
Using the bimetallic combination sBu2Mg?2 LiOR (R=2-ethylhexyl) in toluene enables efficient and regioselective Br/Mg exchanges with various dibromo-arenes and -heteroarenes under mild reaction conditions and provides bromo-substituted magnesiu
Nitrile-substituted 2-(oxazolinyl)-phenols: Minimalistic excited-state intramolecular proton transfer (ESIPT)-based fluorophores
Duvinage, Daniel,G?bel, Dominik,Nachtsheim, Boris J.,Stauch, Tim
supporting information, p. 9213 - 9225 (2020/07/27)
Herein, we present minimalistic single-benzene, excited-state intramolecular proton transfer (ESIPT)-based fluorophores as powerful solid-state emitters. The very simple synthesis gave access to all four regioisomers of nitrile-substituted 2-(oxazolinyl)-
Thiolation of Pyridine-2-sulfonamides using Magnesium Thiolates
Balkenhohl, Moritz,Heinz, Benjamin,Knochel, Paul
, p. 4452 - 4462 (2019/11/21)
The thiolation of pyridine-2-sulfonamides using magnesium thiolates is reported. The ortho-functionalizations of these sulfonamides using TMPMgCl·LiCl (TMP = 2,2,6,6-tetramethylpiperidyl) followed by electrophilic quenching produced a range of 3-functiona
