54416-55-6

Basic information

• Product Name: tris(4-fluorophenyl)cyanurate
• Synonyms: tris(4-fluorophenyl)cyanurate
• CAS NO: 54416-55-6
• Molecular Weight: 411.34
• Mol File: 54416-55-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: tris(4-fluorophenyl)cyanurate(CAS DataBase Reference)
• NIST Chemistry Reference: tris(4-fluorophenyl)cyanurate(54416-55-6)
• EPA Substance Registry System: tris(4-fluorophenyl)cyanurate(54416-55-6)

Safety Data

• Hazardous Substances Data: 54416-55-6(Hazardous Substances Data)

Upstream product

• 108-77-0 1,3,5-trichloro-2,4,6-triazine 
• 371-41-5 4-Fluorophenol 
• 371-35-7 sodium 4-fluorophenoxide 

Downstream Products

• 324-74-3 4-fluoro-biphenyl 
• 462-06-6 fluorobenzene 
• 1194-02-1 4-fluorobenzonitrile 
• 718-25-2 1-fluoro-4-styrylbenzene 

Relevant articles and documents

Nickel-Catalyzed Synthesis of N-(Hetero)aryl Carbamates from Cyanate Salts and Phenols Activated with Cyanuric Chloride

A simple and efficient domino reaction has been designed and employed for the one-pot synthesis of N-(hetero)aryl carbamates through the reaction between alcohols and in-situ produced (hetero)aryl isocyanates in the presence of a nickel catalyst. The phenolic C?O bond was activated via the reaction of phenol with cyanuric chloride (2,4,6-trichloro-1,3,5-triazine (TCT)) as an inexpensive and readily available reagent. This strategy provides practical access to N-(hetero)aryl carbamates in good yields with high functional groups compatibility.

Nickel-catalysed C–O bond reduction of 2,4,6-triaryloxy-1,3,5-triazines in 2-methyltetrahydrofuran

A nickel-catalysed reduction of phenol derivatives activated by 2,4,6-trichloro-1,3,5-triazine (TCT) in ecofriendly 2-methyltetrahydrofuran (2-MeTHF) is described. The phenol-TCT derivatives were readily prepared using grinding method in short time without further purification. This catalytic system allowed the facile C–O cleavage of phenol-TCT derivatives under mild reaction conditions with high efficiency and good functional group tolerance. Gram-scale reaction was also achieved. Particularly, sequential functionalization of phenol-TCT derivatives followed by C–O bond reduction could also be realized, affording the high value-added products in moderate to good yields.

Efficient Ni-catalyzed conversion of phenols protected with 2,4,6-trichloro-1,3,5-triazine (TCT) to olefins

An efficient Ni(COD)2/dppf catalyzed olefination of Ar-O-TCT as synthetic equivalents of aryl halides is described. Activation of C-O bonds in phenols as readily available compounds was achieved with 2,4,6-trichloro-1,3,5-triazine (TCT). This method provides practical access to 1,2-disubstituted olefins in high yields and high functional group compatibility.