718-25-2

Basic information

• Product Name: 1-FLUORO-4-((E)-STYRYL)-BENZENE
• Synonyms: 1-FLUORO-4-((E)-STYRYL)-BENZENE;(E)-4-Fluorostilbene
• CAS NO: 718-25-2
• Molecular Formula: C₁₄H₁₁F
• Molecular Weight: 198.2355432
• Mol File: 718-25-2.mol
• Article Data: 198

Chemical Properties

• Boiling Point: 287.3°C at 760 mmHg
• Flash Point: 124.2°C
• Appearance: /
• Density: 1.12g/cm³
• Vapor Pressure: 0.00433mmHg at 25°C
• Refractive Index: 1.639
• CAS DataBase Reference: 1-FLUORO-4-((E)-STYRYL)-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-FLUORO-4-((E)-STYRYL)-BENZENE(718-25-2)
• EPA Substance Registry System: 1-FLUORO-4-((E)-STYRYL)-BENZENE(718-25-2)

Safety Data

• Hazardous Substances Data: 718-25-2(Hazardous Substances Data)

Usage

Structure

Benzene derivative with a fluorine atom at the 1-position and a styryl group at the 4-position

Type of Compound

Organic compound

Fluorescence Properties

Exhibits fluorescence, useful in materials science and as a fluorescent probe in biological studies

Applications

Building block in organic synthesis, potential use in pharmaceuticals, agrochemicals, and fine chemicals production

Research and Development

Interesting target for research and development in various fields due to its unique structure and properties

InChI:InChI=1/C14H11F/c15-14-10-8-13(9-11-14)7-6-12-4-2-1-3-5-12/h1-11H/b7-6+

Upstream product

• 100-42-5 styrene 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 67300-99-6 1-phenylethenylmagnesium bromide 
• 14655-73-3 N,N,N',N'-tetramethyldiamide of phenylmethanephosphonic acid 
• 405-99-2 para-fluorostyrene 
• 135654-49-8 diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate 
• 5153-69-5 4-fluoro-β-nitrostyrene 
• 100-63-0 phenylhydrazine 
• 768-49-0 (2-methyl-1-propenyl)-benzene 
• 352-34-1 4-fluoro-1-iodobenzene 
• 98-85-1 1-Phenylethanol 
• 352-32-9 p-fluorotoluene 
• 100-39-0 benzyl bromide 
• 39153-68-9 (E,Z)-β-phenoxystyrene 

Downstream Products

• 1436919-11-7 (E)-1-methyl-4-(4-styrylphenoxy)benzene 
• 1448661-17-3 trans-1-(3-phenylpropoxy)-4-styrylbenzene 
• 1448661-26-4 trans-1-ethoxy-4-(4-styrylphenoxy)benzene 
• 1448661-27-5 trans-1-propyl-4-(4-styrylphenoxy)benzene 
• 1448661-28-6 trans-2-(4-styrylphenoxy)naphthalene 
• 24265-92-7 (E)-1-(4-benzyloxyphenyl)-2-phenylethene 
• 1657-46-1 cis-4-fluorostilbene 
• 52881-64-8 2-(4-fluorophenyl)-3-phenyloxirane 
• 345-83-5 4-fluorobenzophenone 
• 3834-66-0 (4-fluorophenyl)phenylethanedione 

Relevant articles and documents

Suzuki coupling reactions in neat water as the solvent: Where in the biphasic reaction mixture do the catalytic reaction steps occur?

Many reports on water-compatible palladium catalysts have appeared in the recent literature. For hydrophobic substrates, mixtures with pure water are biphasic, and it is widely not regarded that the elusive locality of the catalytic process (in water, the

One-Pot Dual Catalysis of a Photoactive Coordination Polymer and Palladium Acetate for the Highly Efficient Cross-Coupling Reaction via Interfacial Electron Transfer

We report herein an exploration of the straightforward one-pot dual-catalysis strategy, i.e., direct combination of a photoactive coordination polymer (CP) with another metal catalyst, for carrying out the desirable photoinduced organic transformation. Th

A photocatalyst-free visible-light-mediated solvent-switchable route to stilbenes/vinyl sulfones from β-nitrostyrenes and arylazo sulfones

Photocatalyst-free visible-light-mediated reactions, based on the presence of a visible-light-absorbing functional group in the starting material itself in order to exclude the often costly, hazardous, degradable and difficult to remove or recover photoredox catalysts, have been gaining momentum recently. We have employed this approach to develop a denitrative photocatalyst-free visible-light-mediated protocol for the arylation/sulfonylation of β-nitrostyrenes employing arylazo sulfones (bench-stable photolabile compounds) in a switchable solvent-controlled manner. Arylazo sulfones served as the aryl and sulfonyl radical precursors under blue LED irradiation for the synthesis oftrans-stilbenes and (E)-vinyl sulfones in CH3CN and dioxane/H2O 2?:?1, respectively. The absence of any metal, photocatalyst and additive; excellent selectivity (E-stereochemistry) and solvent-switchability; and the use of visible light and ambient temperature are the prime assets of the developed method. Moreover, we report the first photocatalyst-free visible light-driven route to synthesize stilbenes and vinyl sulfones from readily available β-nitrostyrenes.