54445-54-4

Basic information

• Product Name: Cyclohexaneacetic acid, 2-methylene-, methyl ester
• CAS NO: 54445-54-4
• Molecular Formula: C10H16O2
• Molecular Weight: 168.236
• Mol File: 54445-54-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexaneacetic acid, 2-methylene-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexaneacetic acid, 2-methylene-, methyl ester(54445-54-4)
• EPA Substance Registry System: Cyclohexaneacetic acid, 2-methylene-, methyl ester(54445-54-4)

Safety Data

• Hazardous Substances Data: 54445-54-4(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 591-49-1 1-methylcyclohex-1-ene 
• 115463-66-6 (6,6-dimethyl-1-cyclohexen-1-yl)methyl acetate 
• 99440-28-5 (6,6-dimethyl-1-cyclohexen-1-yl)methanol 
• 115463-65-5 6,6-dimethyl-1-cyclohexenecarboxaldehyde 
• 64692-82-6 2,2-dimethylcyclohexanone (p-tolylsulfonyl)hydrazone 
• 1193-47-1 2,2-dimethyl-cyclohexanone 
• 54495-73-7 1-(1'-diazo-2'-oxoprop-3'-yl)cyclohexene 
• 36850-80-3 [(1-methoxyvinyl)oxy]trimethylsilane 
• 53723-51-6 1-cyclohexen-1-ylmethyl acetate 
• 67-56-1 methanol 
• 38970-47-7 2-(2-methylenecyclohexyl)acetic acid 
• 53723-52-7 methyl 1-cyclohexene-1-acetate 
• 18294-87-6 1-cyclohexenylacetic acid 

Downstream Products

• 115463-62-2 (1R*,αS*,1'R*)-(+/-)-α-(1'-hydroxyethyl)-2-methylene-1-cyclohexaneacetate 
• 115463-62-2 methyl (1R*,αS*,1'S*)-(+/-)-α-(1'-hydroxyethyl)-2-methylene-1-cyclohexaneacetate 
• 115463-62-2 (1R*,αR*,1'S*)-(+/-)-α-(1'-hydroxyethyl)-2-methylene-1-cyclohexaneacetate 
• 115463-62-2 (1R*,αR*,1'R*)-(+/-)-α-(1'-hydroxyethyl)-2-methylene-cyclohexaneacetate 
• 115463-62-2 Methyl (2R^*,3S^*,1'S^*)-(+/-)-3-hydroxy-2-(2'-methylenecyclohexan-1'-yl)butyrate 
• 115463-62-2 Methyl (2R^*,3R^*,1'S^*)-(+/-)-3-hydroxy-2-(2'-methylenecyclohexan-1'-yl)butyrate 
• 115463-62-2 Methyl (2R^*,3S^*,1'R^*)-(+/-)-3-hydroxy-2-(2'-methylenecyclohexan-1'-yl)butyrate 

Relevant articles and documents

DIRHODIUM TETRAACETATE-CATALYZED DECOMPOSITION OF β,γ-UNSATURATED DIAZO KETONES: A NEW ENTRY TO VINYLOGOUS WOLFF REARRANGEMENT

Dirhodium tetraacetate-catalyzed decomposition of the β,γ-unsaturated diazo ketones 1 - 4, in the presence of methanol, leads to γ,δ-unsaturated esters 5 - 8 via zwitterionic intermediates (i.e., d).

Nucleophile-Selective Iodocyclizations: Butyrolactone versus Tetrahydrofuran Formation

Nucleophile selectivity in the electrophilic cyclization of substrates like 3 has been investigated in the context of efficient chemo- and stereoselective functionalization of 3-hydroxy-2-(2-methylenecyclohexan-1-yl)butyric acids (cf., 6-9) via iodocycliz

Vinylogous Wolff Rearrangement. 4. General Reaction of β,γ-Unsaturated α'-Diazo Ketones

The preparation and vinylogous Wolff rearrangement (VWR) of some 21 acyclic and monocyclic β,γ-unsaturated α'-diazo ketones are described.The resulting γ,δ-unsaturated esters are summarized in Tables I-VI.The rearrangement is promoted by CuSO4, Cu(AcAc)2,