38970-47-7

Basic information

• Product Name: Cyclohexaneacetic acid, 2-methylene-
• CAS NO: 38970-47-7
• Molecular Formula: C9H14O2
• Molecular Weight: 154.209
• Mol File: 38970-47-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexaneacetic acid, 2-methylene-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexaneacetic acid, 2-methylene-(38970-47-7)
• EPA Substance Registry System: Cyclohexaneacetic acid, 2-methylene-(38970-47-7)

Safety Data

• Hazardous Substances Data: 38970-47-7(Hazardous Substances Data)

Upstream product

• 591-49-1 1-methylcyclohex-1-ene 
• 1193-47-1 2,2-dimethyl-cyclohexanone 
• 115463-66-6 (6,6-dimethyl-1-cyclohexen-1-yl)methyl acetate 
• 99440-28-5 (6,6-dimethyl-1-cyclohexen-1-yl)methanol 
• 115463-65-5 6,6-dimethyl-1-cyclohexenecarboxaldehyde 
• 64692-82-6 2,2-dimethylcyclohexanone (p-tolylsulfonyl)hydrazone 
• 108-94-1 cyclohexanone 
• 24731-17-7 ethyl 2-(2-oxocyclohexyl)acetate 
• 53723-51-6 1-cyclohexen-1-ylmethyl acetate 
• 53544-45-9 ethyl (2-methylidenylcyclohexyl)acetate 

Downstream Products

• 128039-93-0 (2-methylenecyclohexyl)acetanilide 
• 139578-17-9 Toluene-4-sulfonic acid (3aR,7aR)-2-oxo-hexahydro-benzofuran-7a-ylmethyl ester 
• 139578-16-8 (2-Formyl-cyclohexyl)-acetic acid ethyl ester 
• 154918-09-9 3-acetoxy-1-(2-methylenecyclohexyl)acetone 
• 154918-08-8 1-Chloro-3-(2-methylene-cyclohexyl)-propan-2-one 
• 2808-75-5 2-methyl-1-methylenecyclohexane 
• 197148-68-8 1-<2-(2-methylenecyclohexyl)acetoxy>-2(1H)-pyridinethione 
• 118227-26-2 4,5-dihydro-4,4-dimethyl-2-<(2-methylenecyclohexyl)methyl>oxazole 
• 54445-54-4 (+/-)-methyl 2-methylene-1-cyclohexaneacetate 

Relevant articles and documents

Pd(II)-catalyzed intramolecular amidoarylation of alkenes with molecular oxygen as sole oxidant

Stereoselective palladium-catalyzed synthesis of structurally versatile indoline derivatives, using molecular oxygen as the sole oxidant, is described. New C-N and C-C bonds form across an alkene in an intramolecular manner. The C-N bond-forming step proceeds via a syn-amidopalladation pathway. The moderate kinetic isotope effects (intramolecular KIE = 3.56) suggest that electrophilic aromatic substitution occurs in the arylation step.

Synthesis and evaluation of cardiotonic activity of simple butenolides II

Three 3-(2-hydroxy-2-methylcyclohexylmethyl)butanolides were synthesized and checked for inotropic activity.Very weak effects were observed for all of them. cardenolide analogues/ butanolides/ inotropic effects

β-hydroxy Esters: (E)- versus (Z)-Enolate Geometry in Dianionic Claisen Rearrangements

Control elements operative in the β-hydroxy ester dianionic Claisen rearrangements are probed.Stereochemistry at Cβ dictates face selectivity at Cα and Cβ' in 1->2-5, but only to the extent that it controls ester enolate g