545379-80-4

Basic information

• Product Name: tris(p-anisyl)ylantimony diacetate
• Synonyms: tris(p-anisyl)ylantimony diacetate
• CAS NO: 545379-80-4
• Molecular Weight: 561.235
• Mol File: 545379-80-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tris(p-anisyl)ylantimony diacetate(CAS DataBase Reference)
• NIST Chemistry Reference: tris(p-anisyl)ylantimony diacetate(545379-80-4)
• EPA Substance Registry System: tris(p-anisyl)ylantimony diacetate(545379-80-4)

Safety Data

• Hazardous Substances Data: 545379-80-4(Hazardous Substances Data)

Upstream product

• 21502-70-5 tris(p-anisyl)antimony 
• 64-19-7 acetic acid 

Downstream Products

• 213596-33-9 2-(4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborolane 
• 3762-33-2 diethyl (p-methoxyphenyl)phosphonate 
• 613-37-6 4-methoxylbiphenyl 
• 92-52-4 biphenyl 
• 2132-80-1 4,4'-Dimethoxybiphenyl 
• 832-01-9 methyl p-methoxycinnamate 
• 7380-78-1 4-(phenylethynyl)anisole 
• 611-94-9 4-Methoxybenzophenone 

Relevant articles and documents

Pd-catalyzed C-arylation of unsaturated compounds with pentavalent triarylantimony dicarboxylates

Triarylantimony (V) derivatives Ar3SbX2 (X = Hal or acyloxy) were prepared by reaction of Ar3Sb with equimolar amounts of a peroxide ROOH (R = t-Bu, H) in the presence of an acid or an anhydride in good to excellent yields. Ar3Sb(O2CR)2 are mild and efficient C-arylation reagents of unsaturated compounds (methyl acrylate, styrene, 2-phenylpropene and acrylonitrile) under palladium catalysis at 50 °C, with PdCl2 being the most effective catalyst. Ar3SbHal2 do not react under these conditions.