5517-61-3

Basic information

• Product Name: methyl 3'-O-benzoyl-β-D-apiofuranoside
• Synonyms: methyl 3'-O-benzoyl-β-D-apiofuranoside
• CAS NO: 5517-61-3
• Molecular Weight: 268.266
• Mol File: 5517-61-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 3'-O-benzoyl-β-D-apiofuranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3'-O-benzoyl-β-D-apiofuranoside(5517-61-3)
• EPA Substance Registry System: methyl 3'-O-benzoyl-β-D-apiofuranoside(5517-61-3)

Safety Data

• Hazardous Substances Data: 5517-61-3(Hazardous Substances Data)

Upstream product

• 52783-53-6 methyl 2,3,3'-tri-O-benzoyl-β-D-apiofuranoside 
• 7473-45-2 1-O-methyl-D-ribofuranose 
• 98-88-4 benzoyl chloride 
• 4099-85-8 ((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methanol 
• 5517-60-2 methyl 3'-O-benzoyl-2,3-O-isopropylidene-β-D-apiofuranoside 

Downstream Products

• 120090-34-8 methyl 5-O-benzoyl-2-O-trityl-β-D-ribofuranoside 
• 120090-35-9 methyl 5-O-benzoyl-3-O-trityl-β-D-ribofuranoside 
• 101024-28-6 methyl 5-O-benzoyl-3-O-benzyl-β-D-ribofuranoside 
• 101024-26-4 methyl 5-O-benzoyl-2-O-benzyl-β-D-ribofuranoside 
• 52783-53-6 methyl 2,3,3'-tri-O-benzoyl-β-D-apiofuranoside 
• 6974-32-9 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose 
• 60084-10-8 tiazofurin 
• 23316-67-8 2,3,5-tri-O-benzoyl-β-D-ribofuranosyl-1-carbonitrile 
• 60084-09-5 ethyl 2-(2',3',3''-tri-O-benzoyl-β-D-apiofuranosyl)thiazole-4-carboxylate 
• 39925-13-8 methyl 1-(2',3',3''-tri-O-benzoyl-apio-β-D-furanosyl)triazole-5-carboxylate 
• 36791-04-5 ribavirin 
• 39925-12-7 methyl 1-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)-1,2,4-triazole-3-carboxylate 
• 120090-36-0 methyl 3-O-acetyl-5-O-benzoyl-2-O-trityl-β-D-ribofuranoside 
• 120090-37-1 methyl 2-O-acetyl-5-O-benzoyl-3-O-trityl-β-D-ribofuranoside 

Relevant articles and documents

Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis

Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by C-C bond formation with net retention of configuration, are obtained. Computational modeling supports a mechanism involving formation of a tetracoordinate borinic ester, which accelerates hydrogen atom transfer with the quinuclidine-derived radical cation through polarity-matching and/or ion-pairing effects.

REGIOSELECTIVE O-DEACYLATION OF FULLY ACYLATED GLYCOSIDES AND 1,2-O-ISOPORPYLIDENEALDOFURANOSE DERIVATIVES WITH HYDRAZINE HYDRATE

On hydrazinolyis in 1:4 acetic acid-pyridine, and in pyridine, partisl O-deacylation of fully acylated methyl glycosides and some other glycosyl compounds ( 23 compounds ) was found to be induced, to give, in good yields, products bearing one free hydroxy