55546-61-7

Basic information

• Product Name: methyl (Z)-3-(phenylthio)but-2-enoate
• Synonyms: methyl (Z)-3-(phenylthio)but-2-enoate
• CAS NO: 55546-61-7
• Molecular Weight: 208.281
• Mol File: 55546-61-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl (Z)-3-(phenylthio)but-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-3-(phenylthio)but-2-enoate(55546-61-7)
• EPA Substance Registry System: methyl (Z)-3-(phenylthio)but-2-enoate(55546-61-7)

Safety Data

• Hazardous Substances Data: 55546-61-7(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 23326-27-4 Methyl 2-butynoate 
• 3186-52-5 O-methyl-S-phenyl thiolcarbonate 
• 74-99-7 prop-1-yne 
• 18913-35-4 methyl buta-2,3-dienoate 
• 2973-86-6 lithium thiophenoxide 
• 930-69-8 sodium thiophenolate 

Relevant articles and documents

Sulfonium Ylides by (3+2) Cycloaddition of Arynes with Vinyl Sulfides: Stereoselective Synthesis of Highly Substituted Alkenes

The reaction of in situ generated arynes with vinyl sulfides provides benzannulated sulfonium ylides in a (3+2) cycloaddition. Trapping of the intermediate ylides with electrophiles (proton transfer or a second aryne addition) and subsequent β-elimination give rise to di-, tri-, or tetrasubstituted alkenes with high stereoselectivity. Experimental studies and DFT calculations provide insight into the mechanisms of these cascade reactions.

Palladium-catalyzed thioesterirication of alkynes with O-methyl S-phenyl thiocarbonate

-

Experimental and Theoretical Study of the Radical-Chain Addition of Benzenethiol to Heterosubstituted Allenes

The radical-chain addition of benzenethiol to phenylallene (PHA), methoxyallene (MEOA), carbomethoxyallene (CBA), cyanoallene (CNA), chloroallene (ClA), and (phenylthio)- and allene (PHSA and MPHSA) has been studied.In all cases, exc