56187-04-3

Basic information

• Product Name: N,N',N''-TRITOSYLDIETHYLENETRIAMINE
• Synonyms: 4-Methyl-N,N-bis(2-(4-MethylphenylsulfonaMido)ethyl)benzenesulfonaMide;4-METHYL-N-{2-[[(4-METHYLPHENYL)SULFONYL](2-{[(4-METHYLPHENYL)SULFONYL]AMINO}ETHYL)AMINO]ETHYL}BENZENESULFONAMIDE;N,N',N''-Tris(p-toluenesulfonyl)diethylenetriamine;N,N',N''-TRITOSYLDIETHYLENETRIAMINE;N,N',N''-TRIS(P-TOLUENESULFIONYL)DIETHYLENETRIAMINE;N,N',N''-TRIS(P-TOLUENESULFONYL)DIETHYLENETRIAMINE;N,N',N''-TRI-P-TOSYLDIETHYLENETRIAMINE, 98%;N N N'-TRIS(P-TOLUENESULFONYL)DIETHYLENETRIAMINE 98+%
• CAS NO: 56187-04-3
• Molecular Formula: C₂₅H₃₁N₃O₆S₃
• Molecular Weight: 565.73
• EINECS: 413-300-5
• Product Categories: Nitrogen Compounds;Organic Building Blocks;Protected Amines
• Mol File: 56187-04-3.mol
• Article Data: 41

Chemical Properties

• Melting Point: 172-176 °C(lit.)
• Boiling Point: 736.9°Cat760mmHg
• Flash Point: 399.5°C
• Appearance: /
• Density: 1.325g/cm³
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 10.38±0.50(Predicted)
• BRN: 1277399
• CAS DataBase Reference: N,N',N''-TRITOSYLDIETHYLENETRIAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: N,N',N''-TRITOSYLDIETHYLENETRIAMINE(56187-04-3)
• EPA Substance Registry System: N,N',N''-TRITOSYLDIETHYLENETRIAMINE(56187-04-3)

Safety Data

• Statements: 53
• Safety Statements: 61
• WGK Germany: 1
• Hazardous Substances Data: 56187-04-3(Hazardous Substances Data)

Usage

Description

N,N',N''-TRITOSYLDIETHYLENETRIAMINE is a chemical compound that is used as a vulcanization catalyst in the production of titanium complexes. It plays a crucial role in the process of vulcanization, which is essential for the manufacturing of various rubber products.

Uses

Used in Rubber Industry:
N,N',N''-TRITOSYLDIETHYLENETRIAMINE is used as a vulcanization catalyst for the production of titanium complexes. Its application is crucial in the vulcanization process, which is an essential step in the manufacturing of various rubber products. The vulcanization process involves the cross-linking of rubber molecules, which enhances the strength, elasticity, and durability of the rubber products. By using N,N',N''-TRITOSYLDIETHYLENETRIAMINE as a vulcanization catalyst, the rubber industry can produce high-quality rubber products with improved performance characteristics.

Upstream product

• 111-40-0 3-azapentane-1,5-diamine 
• 98-59-9 p-toluenesulfonyl chloride 
• 7732-18-5 water 
• 4556-90-5 N-(2-bromo-ethyl)-4-methyl-benzenesulfonamide 
• 4403-78-5 ditosylethylenediamine 
• 70-55-3 toluene-4-sulfonamide 

Downstream Products

• 52667-89-7 N,N',N-tris(p-toluenesulfonyl)-1,4,7-triazacyclononane 
• 105970-63-6 C₃₃H₄₅Cl₂N₃O₈S₃ 
• 96067-64-0 N,N-dimethyltris(p-toluenesulfonyl)-β,β'-diaminodiethylamine 
• 97530-94-4 1,3,6-tritosylperhydro-1,3,6-triazocine 
• 117539-09-0 3-[4,10,16,19,22-Pentakis-(toluene-4-sulfonyl)-1,13-dioxa-4,7,10,16,19,22-hexaaza-cyclotetracos-7-yl]-propionitrile 
• 159789-54-5 1,4,7-tris-(toluene-4-sulfonyl)-[1,4,7]triazecan-9-ol 
• 52601-74-8 N¹,N⁴,N⁷,N¹⁰,N¹³-pentatosyl-1,4,7,10,13-penta-azacyclopentadecane 
• 52667-88-6 cyclen tetratosylate 
• 78668-34-5 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1⁽¹⁴⁾,11⁽¹⁵⁾,12-triene 
• 164987-80-8 8,11,14-Tris-(toluene-4-sulfonyl)-1,4-dioxa-8,11,14-triaza-spiro[4.11]hexadecane 
• 94530-07-1 1,4,7-tris-(4-tolylsulphonyl)-1,4,7,10-tetraazacyclododecane 
• 83076-80-6 1,13-dioxa-4,7,10,16,19,22-hexaaza-4,7,10,16,19,22-hexatosylcyclotetracosane 
• 74461-29-3 N³,N⁶,N⁹-tritosyl-3,6,9-triaza-1,11-undecanediol 
• 115368-17-7 C₂₇H₃₅N₃O₇S₃ 

Relevant articles and documents

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A mononuclear Mn2+ complex based on a novel tris-(ethyl acetate) pendant-armed tetraazamacrocycle: Effect of pyridine on self-assembly and weak interactions

A novel pyridine containing tetraazamacrocycle 3,6,9,15-tetraazabicyclo[9. 3.1]pentadeca-1(15),11,13-triene-3,6,9-triacetic acid ethyl ester (1) and its mononuclear Mn2+ complex (2) have been prepared. Pyridine induced the π-π stacking of [Mn1]2+ and provided donors for nonclassical CH...O hydrogen bonding as well. In the solid state of 2, the combination of π-π interactions and hydrogen bonding constructed a 3D crystal structure and thus formed pairs of interacting mononuclear complexes that mediated weak magnetic exchanges between the Mn2+ ions. Meanwhile, self-assembly of 2 dissociated in the aqueous solution, and the effect of pyridine on the nature of DNA binding with 2 have also been investigated.

Second-Sphere Interaction Promoted Turn-On Fluorescence for Selective Sensing of Organic Amines in a TbIII-based Macrocyclic Framework

Guided by a second-sphere interaction strategy, we fabricated a Tb(III)-based metal—organic framework (MMCF-4) for turn-on sensing of methyl amine with ultra-low detection limit and high turn-on efficiency. MMCF-4 features lanthanide nodes shielded in a nonacoordinate geometry along with secondary coordination spheres that are densely populated with H-bond interacting sites. Nonradiative routes were inhibited by binding-induced rigidification of the ligand on the second coordination sphere, resulting in luminescence amplification. Such remote interacting mechanism involved in the turn-on sensing event was confirmed by single-crystal X-ray diffraction and molecular dynamic simulation studies. The design of both primary and secondary coordination spheres of Tb(III) enabled the first turn-on sensing of organic amines in aqueous conditions. Our work suggests a promising strategy for high-performance turn-on sensing for Ln-MOFs and luminous materials driven by other metal chromophores.

METHOD FOR PREPARING NOTA DERIVATIVE

The present invention discloses Method for preparing NOTA derivative. Firstly, take 4-methylsulfonyl chloride and diethylenetriamine in tosyl group reaction to obtain the first product. And, take the first product and sodium methoxide in the first substitution reaction to obtain the second product. Further, take 4-methylsulfonyl chloride and ethylene glycol in tosyl group reaction to obtain a third product. The second product is coupled to the third product to obtain a fourth product. Take the fourth product and sulfuric acid in the second substitution reaction. Finally, a final product is obtained by a bonding reaction with hydrochloric acid. The preparation method improves the water absorption issue of the benzene ring structure compound (TACN) of the NOTA derivative.