58096-84-7Relevant articles and documents
Platinum-Pyridine Schiff base complexes immobilized onto silica gel as efficient and low cost catalyst for hydrosilylation
Huo, Yingpeng,Hu, Jiwen,Liu, Feng,Wu, Jiapei,Zhang, Yikun,Zhang, Yalan,Wang, Qianyi
, p. 812 - 818 (2021/07/25)
A heterogeneous platinum catalyst with tridentate pyridine Schiff base ligands supported on silica gel is reported. The catalyst was fully characterized via FTIR, solid-state 13C NMR spectroscopy, X-ray photoelectron spectroscopy (XPS), N2 adsorption/desorption analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalyst showed potential application in mediating hydrosilylation reactions between olefins and hydrosilanes, and it can be reused for at least five cycles.
Iridium-Catalyzed Hydrosilylation of Unactivated Alkenes: Scope and Application to Late-Stage Functionalization
Xie, Xingze,Zhang, Xueyan,Yang, Haoyu,Ji, Xin,Li, Jianing,Ding, Shengtao
, p. 1085 - 1093 (2019/01/14)
Highly efficient and general Ir-catalyzed hydrosilylation of unactivated alkenes with excellent anti-Markovnikov regioselectivity was described. A broad scope of hydrosilylated products were synthesized economically and conveniently from commercially or n
Platinum(II) complexes bearing bulky Schiff base ligands anchored onto mesoporous SBA-15 supports as efficient catalysts for hydrosilylation
Huo, Yingpeng,Hu, Jiwen,Lin, Shudong,Ju, Xingming,Wei, Yanlong,Huang, Zhenzhu,Hu, Yangfei,Tu, Yuanyuan
, (2019/04/26)
Reported herein is an easy-to-prepare novel heterogeneous catalyst of platinum complexes bearing binary ligands of bidentate naphthalenolimine and cyclo-1,5-octadiene that are anchored onto mesoporous silica SBA-15. The presence of the binary ligands not only stabilized the platinum, but also enabled the platinum atoms to form nanoclusters with diameters of ca 1?nm, and led to high platinum loading (8.69?wt%). Moreover, the platinum catalyst exhibited high catalytic activity towards hydrosilylation of terminal alkenes and styrene with silanes under mild and solvent-free conditions, with excellent regioselectivity.