60333-76-8Relevant articles and documents
Radical addition of silanes to alkenes followed by oxidation
Palframan, Matthew J.,Parsons, Andrew F.,Johnson, Paul
experimental part, p. 2811 - 2814 (2012/01/06)
Phenyldimethylsilane and trichlorosilane are shown to undergo efficient radical hydrosilylation reactions, on reaction with various alkenes, using triethylborane as the initiator. Adducts from the trichlorosilane reactions can be oxidised to afford alcohols in good yields. This two-step process leads to the anti-Markovnikov hydration of alkenes. Georg Thieme Verlag Stuttgart · New York.
Catalytic activity of bis(dialkylamino)carbenium salts in hydrosilylation reactions
Chernyshev,Belyakova,Sheludyakov,Shevchenko
, p. 1003 - 1006 (2007/10/03)
Bis(dialkylamino)carbenium salts {[(Me2N)2CCl]+}2MCl4 2- (M = Ni, Pd) and {[Me2NC(X)NR2]+}2PtCl62- (R = Me, All; X = H, Cl, Me) are efficient catalysts for hydrosilylation of allyl phenyl ether, triallylamine, allyl chloride, allylamine, and 1-octene with various hydrosilanes. The catalytic activity is dependent on the salt composition and the nature of the metal M, the saturated compound, and the hydrosilane used. The catalysts used are usually insoluble in the reaction mixture, active, and stable. In some cases, carbenium salts are more selective than Speier's catalyst. Novel catalysts, silica-immobilized dialkylaminocarbenium salts, have been prepared. The kinetics of the reaction have been considered.
