58521-27-0Relevant articles and documents
Ni-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Unactivated Phenol and Phenylmethanol Derivatives
Chen, Quan,Wu, Aizhen,Qin, Shengxiang,Zeng, Meiqi,Le, Zhiping,Yan, Zhaohua,Zhang, Hua
supporting information, p. 3239 - 3244 (2018/09/10)
A Ni-catalyzed decarboxylative cross-coupling of potassium polyfluorobenzoates with unactivated phenol and phenylmethanol derivatives is described. This novel transformation provides a practical and efficient protocol towards the synthesis of important polyfluorobiaryls and polyfluorinated diarylmethanes, and greatly enlarges the range of electrophiles utilized in decarboxylative coupling. Remarkably, preliminary mechanistic studies indicated the essential role of Zn(OAc)2 might lie in the enhancement of decarboxylation step. (Figure presented.).
Decarboxylative cross-coupling of mesylates catalyzed by copper/palladium systems with customized imidazolyl phosphine ligands
Song, Bingrui,Knauber, Thomas,Goo?en, Lukas J.
supporting information, p. 2954 - 2958 (2013/04/11)
The activation of the inert C-O bonds in mesylates through the use of a new class of imidazolyl phosphines allows the decarboxylative coupling of aryl mesylates as well as polysubstituted alkenyl mesylates. Variation of the ligands leads to two complementary methods providing the corresponding biaryls and polysubstituted olefins in good yields. Copyright
Copper-catalyzed decarboxylase cross-coupling of potassium polyfluorobenzoates with aryl iodides and bromides
Shang, Rui,Fu, Yao,Wang, Yan,Xu, Qing,Yu, Hai-Zhu,Liu, Lei
supporting information; experimental part, p. 9350 - 9354 (2010/03/04)
Chemical Equitation Presentation For copper only: The decarboxylative cross-coupling of readily accessible and nonvolatile potassium polyfluorobenzoates with aryl iodides and bromides using a copper catalyst provides poly-fluorobiaryls and polyfluorostilb
