74867-23-5

Basic information

• Product Name: 1-(perfluorophenyl)adamantane
• Synonyms: 1-(perfluorophenyl)adamantane
• CAS NO: 74867-23-5
• Molecular Weight: 302.287
• Mol File: 74867-23-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(perfluorophenyl)adamantane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(perfluorophenyl)adamantane(74867-23-5)
• EPA Substance Registry System: 1-(perfluorophenyl)adamantane(74867-23-5)

Safety Data

• Hazardous Substances Data: 74867-23-5(Hazardous Substances Data)

Upstream product

• 768-90-1 1-Adamantyl bromide 
• 58521-27-0 potassium 2,3,4,5,6-pentafluorobenzoate 
• 768-92-3 1-adamantyl fluoride 
• 165612-94-2 bis(pentafluorophenyl)borohydride 
• 392-56-3 Hexafluorobenzene 
• 828-51-3 1-Adamantanecarboxylic acid 
• 768-93-4 1-iodoadamantane 
• 768-95-6 1-adamanthanol 

Relevant articles and documents

Photoredox Polyfluoroarylation of Alkyl Halides via Halogen Atom Transfer

Polyfluoroarene moieties are of interest in medicinal chemistry, agrochemicals, and material sciences. Herein, we present the first polyfluoroarylation of unactivated alkyl halides via a halogen atom transfer process. This method converts primary, secondary, and tertiary alkyl halides into the respective polyfluoroaryl compounds in good yields in the presence of amide, carbamate, ester, aromatic, and sulfonamide moieties, including derivatives of complex bioactive molecules. Mechanistic work revealed that this transformation proceeds through an alkyl radical generated after the halogen atom transfer.

Interactions of C?F Bonds with Hydridoboranes: Reduction, Borylation and Friedel–Crafts Alkylation

The stoichiometric reactions of the alkylfluorides 1-fluoroadamantane (Ad-F), fluorocyclohexane (Cy-F), 1-fluoropentane (Pent-F) and benzyl fluorides with secondary boranes pinacolborane (HBpin), catecholborane (HBcat), 9-borabicyclo(3.3.1)nonane (9-BBN)