58735-82-3Relevant articles and documents
Preparation of Selectively Isotopically Labelled β-Hydroxypropionic Acid
Gutman, Arie L.,Ribon, Vered
, p. 521 - 524 (1986)
Two efficient three-step one-pot procedures for the synthesis of any combination of selectively isotopically labelled β-hydroxypropionic acids from relatively inexpensive labelled sodium acetate and gaseous formaldehyde or carbon dioxide have been developed. -, -, -, -, and -β-hydroxypropionates have been prepared.The question of selective reduction of the intermediate malonate half esters is discussed and the general procedures are described.
NMR study of kinetic HH/HD/DH/DD isotope effects on the tautomerism of acetylporphyrin: Evidence for a stepwise double proton transfer
Schlabach, Martin,Limbach, Hans-Heinrich,Bunnenberg, Edward,Shu, Arthur Y.L.,Tolf, Bo-Ragnar,Djerassi, Carl
, p. 4554 - 4565 (2007/10/02)
The kinetic HH/HD/DH/DD isotope effects of an intramolecular reversible nondegenerate double proton transfer reaction are described. The molecule studied is 8-acetyl-3,13,17-tris[2-(methoxycarbonyl)ethyl]-2,7,12,18-tetramethyl-(21H,23H)- Porphyrin (acetyl