59383-65-2

Basic information

• Product Name: Benzenecarbothioic acid, 4-bromo-, S-(4-chlorophenyl) ester
• CAS NO: 59383-65-2
• Molecular Formula: C13H8BrClOS
• Molecular Weight: 327.629
• Mol File: 59383-65-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 4-bromo-, S-(4-chlorophenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 4-bromo-, S-(4-chlorophenyl) ester(59383-65-2)
• EPA Substance Registry System: Benzenecarbothioic acid, 4-bromo-, S-(4-chlorophenyl) ester(59383-65-2)

Safety Data

• Hazardous Substances Data: 59383-65-2(Hazardous Substances Data)

Upstream product

• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 1122-91-4 4-bromo-benzaldehyde 
• 106-54-7 p-Chlorothiophenol 
• 586-75-4 4-chlorobenzoyl chloride 
• 100874-02-0 <4-Brom-phenacyl>-<4-chlor-phenyl>-sulfid 

Downstream Products

• 844879-16-9 (4-bromophenyl)(3,5-dimethylphenyl)methanone 
• 54118-75-1 4-bromo-4'-methoxybenzophenone 

Relevant articles and documents

Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions

A DTBP-promoted C-H thiolation of aldehydes with disulfides under metal-free and solvent-free conditions is described. The system shows good functional group tolerance to afford thioesters in moderate to excellent yields. the Partner Organisations 2014.

Palladium-catalyzed coupling of thiol esters with aryl and primary and secondary alkyl organoindium reagents

Thiol esters and organoindium reagents undergo palladium-catalyzed cross-coupling under mild conditions to give ketones in moderate to excellent yields. Aryl and primary/ secondary alkyl organoindium reagents can be used as coupling partners. This method has two advantages over the cross-coupling of thiol esters with boron and tin reagents: (1) no added copper reagent is required to mediate the reaction and (2) for the case of alkyl transfer, no added base is required to activate organoindium reagents for cross-coupling as is required for the coupling of alkyl boron reagents with thiol esters.