598-77-6Relevant articles and documents
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Kharasch,Brown
, p. 2142,2146 (1939)
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PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES
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Paragraph 0034-0036, (2013/06/06)
Processes for the production of chlorinated alkanes are provided. The present processes comprise reacting one or more mono- and/or dichloroalkanes to form tri-, tetra- and/or pentachloroalkanes, with high regioselectivity. In those embodiments wherein a dichloroalkane is desirably utilized, it may advantageously be a vicinal dichloroalkane. Further, only one catalyst is utilized. The present processes make use of sulfuryl chloride as a chlorinating agent, rather than a gaseous chlorinating agent such as chlorine gas. Finally, the process uses lower intensity process conditions than at least some conventional processes, and thus, operating costs are saved.
PROCESS FOR THE PRODUCTION OF CHLORINATED PROPANES AND PROPENES
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Paragraph 0042; 0043; 0044, (2013/07/05)
Processes for the production of chlorinated propanes and propenes are provided. The present processes comprise catalyzing at least one chlorination step with one or more regios elective catalysts that provide a regioselectivity to one chloropropane of at least 5: 1 relative to other chloropropanes.