599197-55-4

Basic information

• Product Name: 2-Propen-1-one, 3-(2-bromophenyl)-1-cyclopropyl-, (2E)-
• CAS NO: 599197-55-4
• Molecular Formula: C12H11BrO
• Molecular Weight: 251.123
• Mol File: 599197-55-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 3-(2-bromophenyl)-1-cyclopropyl-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 3-(2-bromophenyl)-1-cyclopropyl-, (2E)-(599197-55-4)
• EPA Substance Registry System: 2-Propen-1-one, 3-(2-bromophenyl)-1-cyclopropyl-, (2E)-(599197-55-4)

Safety Data

• Hazardous Substances Data: 599197-55-4(Hazardous Substances Data)

Upstream product

• 765-43-5 Cyclopropyl methyl ketone 
• 6630-33-7 ortho-bromobenzaldehyde 
• 112849-15-7 (2-cyclopropyl-2-oxoethyl) (triphenyl)phosphonium bromide 

Relevant articles and documents

Asymmetric transfer hydrogenation of cycloalkyl vinyl ketones to allylic alcohols catalyzed by ruthenium amido complexes

A chemoselective 1,2-reduction of cycloalkyl vinyl ketones via asymmetric transfer hydrogenation is described. The reduction proceeded smoothly with a chiral diamine ruthenium complex as a catalyst and a HCOOH-NEt3 azeotrope as both a hydrogen source and solvent under mild conditions. A wide range of 1-cycloalkyl chiral allylic alcohols were obtained in good yields and up to 87% ee. It was found that the alkyl group plays an important role in the enantioselectivity.